/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 77 Gasoline is composed primarily o... [FREE SOLUTION] | 91影视

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Gasoline is composed primarily of hydrocarbons, including many with eight carbon atoms, called octanes. One of the cleanest-burning octanes is a compound called 2,3,4 trimethylpentane, which has the following structural formula: The complete combustion of one mole of this compound to \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(g)\) leads to \(\Delta H^{\circ}=-5064.9 \mathrm{~kJ} / \mathrm{mol}\) (a) Write a balanced equation for the combustion of \(1 \mathrm{~mol}\) of \(\mathrm{C}_{8} \mathrm{H}_{18}(l) .(\mathbf{b})\) Write a balanced equation for the formation of \(\mathrm{C}_{8} \mathrm{H}_{18}(l)\) from its elements. (c) By using the information in this problem and data in Table \(5.3,\) calculate \(\Delta H_{f}^{\circ}\) for 2,3,4 trimethylpentane.

Short Answer

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The short answer to the given question is: (a) The balanced equation for the combustion of 1 mol of C鈧圚鈧佲倛 is: \[ C_{8}H_{18}(l) + \frac{25}{2}O_{2}(g) \rightarrow 8CO_{2}(g) + 9H_{2}O(g) \] (b) The balanced equation for the formation of C鈧圚鈧佲倛 from its elements is: \[ 8C(graphite) + 9H_{2}(g) \rightarrow C_{8}H_{18}(l) \] (c) The standard enthalpy of formation, 螖Hf掳, for 2,3,4 trimethylpentane is -259.3 kJ/mol.

Step by step solution

01

Combustion Reaction Equation

The combustion of a hydrocarbon involves a reaction with oxygen (O鈧) to produce carbon dioxide (CO鈧) and water (H鈧侽). When balanced, the equation for the combustion of 2,3,4 trimethylpentane can be written as: \[ C_{8}H_{18}(l) + \frac{25}{2}O_{2}(g) \rightarrow 8CO_{2}(g) + 9H_{2}O(g) \] Step 2: Write the balanced equation for the formation of C鈧圚鈧佲倛 from its elements
02

Formation Reaction Equation

To write the balanced equation for the formation of C鈧圚鈧佲倛 from its elements, we need to combine carbon (C) and hydrogen (H鈧) to produce C鈧圚鈧佲倛. Since carbon is in its standard state as graphite and hydrogen is diatomic, the balanced equation is: \[ 8C(graphite) + 9H_{2}(g) \rightarrow C_{8}H_{18}(l) \] Step 3: Calculate the standard enthalpy of formation, 螖Hf掳, of 2,3,4 trimethylpentane
03

Calculating 螖Hf掳 for C鈧圚鈧佲倛

We are given the enthalpy change for the combustion reaction, which is -5064.9 kJ/mol. We also need the enthalpies of formation for CO鈧 and H鈧侽 from Table 5.3. Here they are: 螖Hf掳(CO鈧) = -393.5 kJ/mol 螖Hf掳(H鈧侽) = -241.8 kJ/mol The reaction enthalpy for the formation of C鈧圚鈧佲倛 can be expressed as follows: 螖Hf掳(C鈧圚鈧佲倛) = 危[螖Hf掳(products)] - 危[螖Hf掳(reactants)] Using the given data (-5064.9 kJ/mol), data from Table 5.3, and our balanced equations, we can calculate the 螖Hf掳 for C鈧圚鈧佲倛: 螖Hf掳(C鈧圚鈧佲倛) = [8螖Hf掳(CO鈧) + 9螖Hf掳(H鈧侽)] - [螖Hrxn掳] 螖Hf掳(C鈧圚鈧佲倛) = [8(-393.5 kJ/mol) + 9(-241.8 kJ/mol)] - [-5064.9 kJ/mol] 螖Hf掳(C鈧圚鈧佲倛) = (-3148 kJ +(-2176.2 kJ)) + 5064.9 kJ/mol 螖Hf掳(C鈧圚鈧佲倛) = -259.3 kJ/mol So, the standard enthalpy of formation for 2,3,4 trimethylpentane is -259.3 kJ/mol.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Combustion Reaction Equations
A combustion reaction is an exothermic chemical reaction where a substance, typically a hydrocarbon, reacts with oxygen to produce carbon dioxide, water, and energy in the form of heat or light.

In the given exercise, we're looking at the combustion of a hydrocarbon named 2,3,4 trimethylpentane. The general formula for the combustion of a hydrocarbon is \[ \text{Hydrocarbon} + \text{O}_2 \rightarrow \text{CO}_2 + \text{H}_2\text{O} \.\]
The combustion of 2,3,4 trimethylpentane is specifically represented by the equation:\
\[ C_{8}H_{18}(l) + \frac{25}{2}O_{2}(g) \rightarrow 8CO_{2}(g) + 9H_{2}O(g) \]
This balanced equation shows that one mole of 2,3,4 trimethylpentane reacts with oxygen to produce eight moles of carbon dioxide and nine moles of water vapor.

An essential aspect of understanding these reactions is ensuring that they are properly balanced, meaning the number of atoms for each element is equal on both sides of the equation. For students struggling with this concept, remember that coefficients can be used to balance the atoms, as demonstrated in the step-by-step solution.
Formation Reaction Equations Made Simple
A formation reaction involves the production of a compound from its elements in their standard states. The standard state is the form in which the element is most stable under standard conditions (1 atm pressure and usually at 25掳C).

For the formation of an organic compound like 2,3,4 trimethylpentane, the equation involves carbon and hydrogen. Here, carbon is typically represented as graphite, the most stable form of carbon under standard conditions, and hydrogen is diatomic (H鈧).
Thus, the balanced formation reaction for 2,3,4 trimethylpentane from its elements is given by:\
\[ 8C(graphite) + 9H_{2}(g) \rightarrow C_{8}H_{18}(l) \]
This equation shows that eight atoms of carbon from graphite react with 18 atoms of hydrogen from diatomic hydrogen molecules to form one mole of 2,3,4 trimethylpentane liquid.

To help students grasp the balancing aspect, focus on the fact that each carbon atom will form one-eighth of the hydrocarbon compound, and that two hydrogen atoms will form one molecule of diatomic hydrogen, H鈧. It is important to match both the types and numbers of atoms on each side of the equation for it to be balanced.
Standard Enthalpy Change Explained
The standard enthalpy change, \( \Delta H^\circ \), represents the heat exchanged in a reaction at constant pressure when all reactants and products are in their standard states.

For reactions, the standard enthalpy change can be calculated using Hess's law, which states that the total enthalpy change for a reaction is the sum of the enthalpy changes for individual steps that lead to the overall reaction.
In the context of our exercise, the standard enthalpy of formation, \( \Delta H_f^\circ \), for 2,3,4 trimethylpentane can be calculated by considering the standard enthalpy changes of the combustion products and then rearranging the equation to solve for the unknown formation enthalpy. The equation for this process is: \[ \Delta H_f^\circ(\text{compound}) = \Sigma[\Delta H_f^\circ(\text{products})] - \Sigma[\Delta H_f^\circ(\text{reactants})] \]
With given values for the combustion of 2,3,4 trimethylpentane and the formation enthalpies of CO鈧 and H鈧侽, we deduce the heat needed to form 2,3,4 trimethylpentane.

If students find this calculation challenging, it may be helpful to visualize the reaction in terms of bond breaking and forming 鈥 breaking bonds requires energy (endothermic) and forming bonds releases energy (exothermic). This visualization can make understanding enthalpy changes more intuitive.

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Most popular questions from this chapter

Diethyl ether, \(\mathrm{C}_{4} \mathrm{H}_{10} \mathrm{O}(l),\) a flammable compound that has long been used as a surgical anesthetic, has the structure \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{O}-\mathrm{CH}_{2}-\mathrm{CH}_{3}\) The complete combustion of \(1 \mathrm{~mol}\) of \(\mathrm{C}_{4} \mathrm{H}_{10} \mathrm{O}(l)\) to \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(l)\) yields \(\Delta H^{\circ}=-2723.7 \mathrm{~kJ}\). (a) Write a balanced equation for the combustion of \(1 \mathrm{~mol}\) of \(\mathrm{C}_{4} \mathrm{H}_{10} \mathrm{O}(l)\) (b) Write a balanced equation for the formation of \(\mathrm{C}_{4} \mathrm{H}_{10} \mathrm{O}(l)\) from its elements. (c) By using the information in this problem and data in Table \(5.3,\) calculate \(\Delta H_{f}^{\circ}\) for diethyl ether.

The decomposition of slaked lime, \(\mathrm{Ca}(\mathrm{OH})_{2}(s),\) into lime, \(\mathrm{CaO}(s),\) and \(\mathrm{H}_{2} \mathrm{O}(g)\) at constant pressure requires the addition of \(109 \mathrm{~kJ}\) of heat per mole of \(\mathrm{Ca}(\mathrm{OH})_{2}\). (a) Write a balanced thermochemical equation for the reaction. (b) Draw an enthalpy diagram for the reaction.

(a) What are the units of molar heat capacity? (b) What are the units of specific heat? (c) If you know the specific heat of copper, what additional information do you need to calculate the heat capacity of a particular piece of copper pipe?

(a) What is meant by the term standard conditions with reference to enthalpy changes? (b) What is meant by the term enthalpy of formation? (c) What is meant by the term standard enthalpy of formation?

(a) Why are tables of standard enthalpies of formation so useful? (b) What is the value of the standard enthalpy of formation of an element in its most stable form? (c) Write the chemical equation for the reaction whose enthalpy change is the standard enthalpy of formation of sucrose (table sugar), \(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}(s), \Delta H_{f}^{\circ}\left[\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right]\)

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