Chapter 4: Problem 45
Define oxidation and reduction in terms of (a) electron transfer and (b) oxidation numbers.
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Chapter 4: Problem 45
Define oxidation and reduction in terms of (a) electron transfer and (b) oxidation numbers.
These are the key concepts you need to understand to accurately answer the question.
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A sample of \(5.53 \mathrm{~g}\) of \(\mathrm{Mg}(\mathrm{OH})_{2}\) is added to \(25.0 \mathrm{~mL}\) of 0.200 \(\mathrm{M} \mathrm{HNO}_{3}\) (a) Write the chemical equation for the reaction that occurs. (b) Which is the limiting reactant in the reaction? (c) How many moles of \(\mathrm{Mg}(\mathrm{OH})_{2}, \mathrm{HNO}_{3},\) and \(\mathrm{Mg}\left(\mathrm{NO}_{3}\right)_{2}\) are present after the reaction is complete?
We have learned in this chapter that many ionic solids dissolve in water as strong electrolytes, that is, as separated ions in solution. What properties of water facilitate this process? Would you expect ionic compounds to be soluble in elemental liquids like bromine or mercury, just as they are in water? Explain.
Magnesium carbonate, magnesium oxide, and magnesium hydroxide are all white solids that react with acidic solutions. (a) Write a balanced molecular equation and a net ionic equation for the reaction that occurs when each substance reacts with a hydrochloric acid solution. (b) By observing the reactions in part (a) could you distinguish any of the three magnesium substances from the other two? If so how? (c) If excess \(\mathrm{HCl}(a q)\) is added, would the clear solutions left behind after the reaction is complete contain the same or different ions in each case?
Using the activity series (Table 4.5 ), write balanced chemical equations for the following reactions. If no reaction occurs, simply write NR. (a) Nickel metal is added to a solution of copper(II) nitrate; (b) a solution of zinc nitrate is added to a solution of magnesium sulfate; (c) hydrochloric acid is added to gold metal; (d) chromium metal is immersed in an aqueous solution of cobalt(II) chloride; (e) hydrogen gas is bubbled through a solution of silver nitrate.
Indicate the concentration of each ion or molecule present in the following solutions: (a) \(0.25 \mathrm{M} \mathrm{NaNO}_{3}\), (b) \(1.3 \times 10^{-2} \mathrm{M}\) \(\mathrm{MgSO}_{4}\), (c) \(0.0150 \mathrm{M} \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\), (d) a mixture of \(45.0 \mathrm{~mL}\) of \(0.272 \mathrm{M} \mathrm{NaCl}\) and \(65.0 \mathrm{~mL}\) of \(0.0247 \mathrm{M}\left(\mathrm{NH}_{4}\right)_{2} \mathrm{CO}_{3} .\) Assume that the volumes are additive.
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