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Write a balanced chemical equation for the reaction that occurs when (a) calcium metal undergoes a combination reaction with \(\mathrm{O}_{2}(g) ;\) (b) copper(II) hydroxide decomposes into copper(II) oxide and water when heated; (c) heptane, \(\mathrm{C}_{7} \mathrm{H}_{16}(l),\) burns in air; (d) methyl tert-butyl ether, \(\mathrm{C}_{5} \mathrm{H}_{12} \mathrm{O}(l)\) burns in air.

Short Answer

Expert verified
(a) 2Ca + O鈧 鈫 2CaO (b) Cu(OH)鈧 鈫 CuO + H鈧侽 (c) C鈧嘓鈧佲倖 + 11O鈧 鈫 7CO鈧 + 8H鈧侽 (d) C鈧匟鈧佲倐O + 6O鈧 鈫 5CO鈧 + 6H鈧侽

Step by step solution

01

Reaction (a): Calcium metal and oxygen gas.

In this reaction, calcium metal (Ca) reacts with oxygen gas (O鈧) to form calcium oxide (CaO). The unbalanced equation is: Ca + O鈧 鈫 CaO To balance the equation, we need to have 2 oxygen atoms on both sides. We can achieve this by placing a 2 in front of CaO: Ca + O鈧 鈫 2CaO The balanced equation for this reaction is: 2Ca + O鈧 鈫 2CaO
02

Reaction (b): Decomposition of copper(II) hydroxide.

Copper(II) hydroxide (Cu(OH)鈧) decomposes upon heating to produce copper(II) oxide (CuO) and water (H鈧侽). The unbalanced equation is: Cu(OH)鈧 鈫 CuO + H鈧侽 Balancing the equation, we realize that the number of atoms for each element is already equal on both sides. Therefore, the balanced equation for this reaction is: Cu(OH)鈧 鈫 CuO + H鈧侽
03

Reaction (c): Combustion of heptane.

Heptane (C鈧嘓鈧佲倖) reacts with oxygen gas (O鈧) when burned in air to produce carbon dioxide (CO鈧) and water (H鈧侽). The unbalanced equation is: C鈧嘓鈧佲倖 + O鈧 鈫 CO鈧 + H鈧侽 To balance the equation, first balance the carbon and hydrogen atoms: C鈧嘓鈧佲倖 + O鈧 鈫 7CO鈧 + 8H鈧侽 Finally, balance the oxygen atoms by placing a 11 in front of O鈧: C鈧嘓鈧佲倖 + 11O鈧 鈫 7CO鈧 + 8H鈧侽 The balanced equation for this reaction is: C鈧嘓鈧佲倖 + 11O鈧 鈫 7CO鈧 + 8H鈧侽
04

Reaction (d): Combustion of methyl tert-butyl ether.

Methyl tert-butyl ether (C鈧匟鈧佲倐O) reacts with oxygen gas (O鈧) when burned in air to produce carbon dioxide (CO鈧) and water (H鈧侽). The unbalanced equation is: C鈧匟鈧佲倐O + O鈧 鈫 CO鈧 + H鈧侽 To balance the equation, first balance the carbon and hydrogen atoms: C鈧匟鈧佲倐O + O鈧 鈫 5CO鈧 + 6H鈧侽 Finally, balance the oxygen atoms by placing a 6 in front of O鈧: C鈧匟鈧佲倐O + 6O鈧 鈫 5CO鈧 + 6H鈧侽 The balanced equation for this reaction is: C鈧匟鈧佲倐O + 6O鈧 鈫 5CO鈧 + 6H鈧侽

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Combination Reaction
A combination reaction, also known as a synthesis reaction, involves two or more substances reacting to form a single new product. These reactions are one of the simplest types of chemical reactions. An example from the exercise is the reaction of calcium metal with oxygen gas to form calcium oxide.

To write the balanced equation for this reaction, we start with the substances involved:
  • Calcium (Ca) - the metal reactant.
  • Oxygen (O鈧) - the gaseous reactant.
  • Calcium Oxide (CaO) - the product.
The unbalanced equation may look like this:\[\text{Ca} + \text{O鈧倉 \rightarrow \text{CaO}\]
To balance the equation, count the atoms on each side and adjust the coefficients accordingly. In this case, balance the oxygen by placing a 2 in front of CaO, making it:\[\text{Ca} + \text{O鈧倉 \rightarrow 2\text{CaO}\]
Further adjust the... by placing a 2 in front of Ca, resulting in:\[2\text{Ca} + \text{O鈧倉 \rightarrow 2\text{CaO}\]This equation is now balanced, with equal numbers of Ca and O on both sides.

Combination reactions often release energy, making them exothermic. These reactions are common in forming compounds in nature.
Decomposition Reaction
Decomposition reactions are the opposite of combination reactions. In decomposition reactions, a single compound breaks down into two or more simpler substances. This type of reaction usually requires energy input, like heat, to occur.

An informative example from the given exercise is the decomposition of copper(II) hydroxide. When heated, it decomposes into copper(II) oxide and water.
  • Copper(II) Hydroxide (Cu(OH)鈧) - the compound undergoing decomposition.
  • Copper(II) Oxide (CuO) - one of the products.
  • Water (H鈧侽) - another product.
The initial unbalanced equation is:\[\text{Cu(OH)鈧倉 \rightarrow \text{CuO} + \text{H鈧侽}\]
In this equation, notice the number of atoms for each element on both sides of the equation:
  • 1 Copper atom on each side.
  • 2 Oxygen atoms from Cu(OH)鈧 turning into one CuO and one H鈧侽, totaling two Oxygen atoms.
  • 2 Hydrogen atoms in the water molecule, matching the 2 from the hydroxide groups.
This equation is already balanced as is. Decomposition reactions are crucial in various applications, including recycling and the breakdown of organic materials.
Combustion Reaction
Combustion reactions are usually the burning of substances in the presence of oxygen. They generate heat and light, making them exothermic processes. In combustion, organic compounds often convert into carbon dioxide and water.

An example from the exercise is the combustion of heptane. Heptane, a hydrocarbon, reacts with oxygen to form carbon dioxide and water.
  • Heptane (C鈧嘓鈧佲倖) - the hydrocarbon fuel.
  • Oxygen (O鈧) - the oxidizing agent causing the burn.
  • Carbon Dioxide (CO鈧) and Water (H鈧侽) - the products resulting from complete combustion.
The unbalanced reaction is:\[\text{C鈧嘓鈧佲倖} + \text{O鈧倉 \rightarrow \text{CO鈧倉 + \text{H鈧侽}\]
To balance it, adjust the carbon and hydrogen atoms first:\[\text{C鈧嘓鈧佲倖} + \text{O鈧倉 \rightarrow 7\text{CO鈧倉 + 8\text{H鈧侽}\]
Then, ensure there are enough oxygen molecules by placing an 11 in front of O鈧:\[\text{C鈧嘓鈧佲倖} + 11\text{O鈧倉 \rightarrow 7\text{CO鈧倉 + 8\text{H鈧侽}\]
Finally, your equation is balanced! Combustion reactions are vital for energy production in engines as well as cooking and heating processes. Proper balancing ensures an understanding of the stoichiometry involved, which is crucial for efficient energy use.

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Most popular questions from this chapter

Write balanced chemical equations to correspond to each of the following descriptions: (a) When sulfur trioxide gas reacts with water, a solution of sulfuric acid forms. (b) Boron sulfide, \(\mathrm{B}_{2} \mathrm{~S}_{3}(s),\) reacts violently with water to form dissolved boric acid, \(\mathrm{H}_{3} \mathrm{BO}_{3},\) and hydrogen sulfide gas. (c) Phosphine, \(\mathrm{PH}_{3}(g)\), combusts in oxygen gas to form water vapor and solid tetraphosphorus decaoxide. (d) When solid mercury(II) nitrate is heated, it decomposes to form solid mercury(II) oxide, gaseous nitrogen dioxide, and oxygen. (e) Copper metal reacts with hot concentrated sulfuric acid solution to form aqueous copper(II) sulfate, sulfur dioxide gas, and water.

Determine the empirical formulas of the compounds with the following compositions by mass: (a) \(10.4 \% \mathrm{C}, 27.8 \% \mathrm{~S},\) and \(61.7 \% \mathrm{Cl}\) (b) \(21.7 \% \mathrm{C}, 9.6 \% \mathrm{O},\) and \(68.7 \% \mathrm{~F}\) (c) \(32.79 \% \mathrm{Na}, 13.02 \% \mathrm{Al},\) and the remainder \(\mathrm{F}\)

A mixture containing \(\mathrm{KClO}_{3}, \mathrm{~K}_{2} \mathrm{CO}_{3}, \mathrm{KHCO}_{3},\) and \(\mathrm{KCl}\) was heated, producing \(\mathrm{CO}_{2}, \mathrm{O}_{2}\), and \(\mathrm{H}_{2} \mathrm{O}\) gases according to the following equations: $$ \begin{aligned} 2 \mathrm{KClO}_{3}(s) & \longrightarrow 2 \mathrm{KCl}(s)+3 \mathrm{O}_{2}(g) \\\ 2 \mathrm{KHCO}_{3}(s) & \longrightarrow \mathrm{K}_{2} \mathrm{O}(s)+\mathrm{H}_{2} \mathrm{O}(g)+2 \mathrm{CO}_{2}(g) \\ \mathrm{K}_{2} \mathrm{CO}_{3}(s) & \longrightarrow \mathrm{K}_{2} \mathrm{O}(s)+\mathrm{CO}_{2}(g) \end{aligned} $$ The KCl does not react under the conditions of the reaction. If \(100.0 \mathrm{~g}\) of the mixture produces \(1.80 \mathrm{~g}\) of \(\mathrm{H}_{2} \mathrm{O}, 13.20 \mathrm{~g}\) of \(\mathrm{CO}_{2}\), and \(4.00 \mathrm{~g}\) of \(\mathrm{O}_{2}\), what was the composition of the original mixture? (Assume complete decomposition of the mixture.)

Write a balanced chemical equation for the reaction that occurs when (a) \(\mathrm{Mg}(s)\) reacts with \(\mathrm{Cl}_{2}(g) ;\) (b) barium carbonate decomposes into barium oxide and carbon dioxide gas when heated; \((\mathbf{c})\) the hydrocarbon styrene, \(\mathrm{C}_{8} \mathrm{H}_{8}(l)\), is combusted in air; (d) dimethylether, \(\mathrm{CH}_{3} \mathrm{OCH}_{3}(g)\), is combusted in air.

Epsom salts, a strong laxative used in veterinary medicine, is a hydrate, which means that a certain number of water molecules are included in the solid structure. The formula for Epsom salts can be written as \(\mathrm{MgSO}_{4} \cdot x \mathrm{H}_{2} \mathrm{O},\) where \(x\) indicates the number of moles of \(\mathrm{H}_{2} \mathrm{O}\) per mole of \(\mathrm{MgSO}_{4}\). When \(5.061 \mathrm{~g}\) of this hydrate is heated to \(250{ }^{\circ} \mathrm{C},\) all the water of hydration is lost, leaving \(2.472 \mathrm{~g}\) of \(\mathrm{MgSO}_{4}\). What is the value of \(x ?\)

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