Chapter 23: Problem 57
A classmate says, "A weak-field ligand usually means the complex is high spin." Is your classmate correct? Explain.
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Chapter 23: Problem 57
A classmate says, "A weak-field ligand usually means the complex is high spin." Is your classmate correct? Explain.
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Although the cis configuration is known for \(\left[\mathrm{Pt}(\mathrm{en}) \mathrm{Cl}_{2}\right], \mathrm{no}\) trans form is known. (a) Explain why the trans compound is not possible. (b) Would \(\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\) be more likely than en \(\left(\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\right)\) to form the trans compound? Explain.
Consider an octahedral complex \(\mathrm{MA}_{3} \mathrm{~B}_{3} .\) How many geometric isomers are expected for this compound? Will any of the isomers be optically active? If so, which ones?
A Cu electrode is immersed in a solution that is \(1.00 \mathrm{M}\) in \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+}\) and \(1.00 \mathrm{M}\) in \(\mathrm{NH}_{3}\). When the cathode is a standard hydrogen electrode, the emf of the cell is found to be \(+0.08 \mathrm{~V}\). What is the formation constant for \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+} ?\)
Generally speaking, for a given metal and ligand, the stability of a coordination compound is greater for the metal in the +3 rather than in the +2 oxidation state (for metals that form stable +3 ions in the first place). Suggest an explanation, keeping in mind the Lewis acid-base nature of the metal-ligand bond.
Suppose that a transition-metal ion was in a lattice in which it was in contact with just two nearby anions, located on opposite sides of the metal. Diagram the splitting of the metal \(\bar{d}\) orbitals that would result from such a crystal field. Assuming a strong field, how many unpaired electrons would you expect for a metal ion with six \(d\) electrons? (Hint: Consider the linear axis to be the \(z\) -axis)
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