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Predict whether each of the following compounds is molecular or ionic: (a) \(\mathrm{B}_{2} \mathrm{H}_{6},\) (b) \(\mathrm{CH}_{3} \mathrm{OH},\) (c) \(\mathrm{LiNO}_{3},\) (d) \(\mathrm{Sc}_{2} \mathrm{O}_{3}\), (e) \(\mathrm{CsBr}\), (f) \(\mathrm{NOCl},(\mathrm{g}) \mathrm{NF}_{3}\) (h) \(\mathrm{Ag}_{2} \mathrm{SO}_{4}\)

Short Answer

Expert verified
(a) B2H6: molecular, (b) CH3OH: molecular, (c) LiNO3: ionic, (d) Sc2O3: ionic, (e) CsBr: ionic, (f) NOCl: molecular, (g) NF3: molecular, (h) Ag2SO4: ionic

Step by step solution

01

(a) B2H6

Elements B (boron) and H (hydrogen) are both non-metals, and their electronegativity difference is 2.06 - 1.57 = 0.49, which is less than 1.7, indicating that B2H6 is a molecular compound.
02

(b) CH3OH

Elements C (carbon), H (hydrogen), and O (oxygen) are all non-metals, and the electronegativity differences between C-H (0.35), C-O (1.43), and H-O (1.24) are all less than 1.7, indicating that CH3OH is a molecular compound.
03

(c) LiNO3

Elements Li (lithium) and N (nitrogen), O (oxygen) are metal and non-metals, respectively. The electronegativity difference between Li and N (1.94), Li and O (2.08) demonstrate that LiNO3 is an ionic compound.
04

(d) Sc2O3

Elements Sc (scandium) is a metal, and O (oxygen) is a non-metal. The electronegativity difference between Sc and O (1.61) is close to 1.7. In this case, Sc2O3 is considered an ionic compound as it consists of a metal and non-metal.
05

(e) CsBr

Elements Cs (cesium) is a metal, and Br (bromine) is a non-metal. The electronegativity difference between Cs and Br (2.36) is greater than 1.7, indicating that CsBr is an ionic compound.
06

(f) NOCl

Elements N (nitrogen), O (oxygen), and Cl (chlorine) are all non-metals, and their electronegativity differences (N-O: 0.51, N-Cl: 0.64, O-Cl: 0.13) are all less than 1.7, indicating that NOCl is a molecular compound.
07

(g) NF3

Elements N (nitrogen) and F (fluorine) are non-metals, and their electronegativity difference (0.98) is less than 1.7, indicating that NF3 is a molecular compound.
08

(h) Ag2SO4

Elements Ag (silver) is a metal, and S (sulfur), O (oxygen) are non-metals. The electronegativity difference between Ag and S (1.45), Ag and O (1.75), indicates that Ag2SO4 is an ionic compound. In summary, compounds (a), (b), (f), and (g) are molecular compounds, while (c), (d), (e), and (h) are ionic compounds.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Electronegativity
Electronegativity is a key concept that helps us understand how atoms interact with each other to form compounds. It is the tendency of an atom to attract electrons towards itself when it forms a chemical bond. Different elements have different electronegativity values, and these values determine the type of bond that will form between atoms.

A higher electronegativity indicates a stronger attraction for electrons. The Pauling scale is commonly used for measuring electronegativity, with values ranging from approximately 0.7 for francium to 3.98 for fluorine. When determining whether a compound is ionic or molecular, comparing the electronegativity values of the elements involved is crucial.

  • If the difference in electronegativity between two atoms is greater than 1.7, the bond is typically ionic.
  • If the difference is less than 1.7, it is more likely to be a covalent bond, resulting in a molecular compound.
Understanding electronegativity allows us to predict the nature of the bonds in a compound, which is vital for identifying the compound's properties and behavior.
Chemical Bonding
Chemical bonding is the process by which atoms combine to form compounds and molecules. This can occur through the sharing, gaining, or losing of electrons, resulting in different types of bonds.

There are primarily three types of chemical bonds:
  • Ionic Bonds: Formed when electrons are transferred from one atom to another, leading to the formation of ions. These bonds are typical in ionic compounds and occur between metals and non-metals. The resulting compound is usually crystalline and has a high melting point.
  • Covalent Bonds: Occur when atoms share electrons. These bonds are found in molecular compounds and usually involve non-metals. Covalent bonding results in a wide variety of substances, from gases like oxygen to solids like sugar.
  • Metallic Bonds: Involve the pooling of electrons among a lattice of metal atoms. This type of bond gives metals their characteristic properties, such as conductivity and malleability.
Understanding chemical bonding is essential for predicting physical and chemical properties of substances and for understanding the structure of materials.
Compounds
Compounds are substances formed when two or more elements are chemically bonded together. They can be classified based on the types of bonds that hold their atoms together.

  • Molecular Compounds: These are formed by covalent bonds, where atoms share electrons. They often consist of non-metal elements and can exist as gases, liquids, or solids. An example is water (\(H_2O\)).
  • Ionic Compounds: Composed of ions held together by ionic bonds, where electrons are transferred between atoms. Typically formed between metals and non-metals, they usually form crystalline solids with high melting and boiling points. An example is table salt (NaCl).
Compounds have distinct properties that are different from the individual elements that compose them. Understanding compounds helps us harness their unique properties for various applications, from creating new materials to understanding biological processes.

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Most popular questions from this chapter

How many hydrogen atoms are in each of the following: (a) \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH},\) (b) \(\mathrm{Ca}\left(\mathrm{CH}_{3} \mathrm{COO}\right)_{2},\) (c) \(\left(\mathrm{NH}_{4}\right)_{3} \mathrm{PO}_{4} ?\)

Gallium (Ga) consists of two naturally occurring isotopes with masses of 68.926 and 70.925 amu. (a) How many protons and neutrons are in the nucleus of each isotope? Write the complete atomic symbol for each, showing the atomic number and mass number. (b) The average atomic mass of Ga is 69.72 amu. Calculate the abundance of each isotope.

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Each of the following elements is capable of forming an ion in chemical reactions. By referring to the periodic table, predict (b) \(\mathrm{Al},(\mathbf{c}) \mathrm{K}\) the charge of the most stable ion of each: (a) \(\mathrm{Mg}\), (d) S, (e) \(\mathrm{F}\).

How did Rutherford interpret the following observations made during his \(\alpha\) -particle scattering experiments? (a) Most \(\alpha\) particles were not appreciably deflected as they passed through the gold foil. (b) A few \(\alpha\) particles were deflected at very large angles. (c) What differences would you expect if beryllium foil were used instead of gold foil in the \(\alpha\) -particle scattering experiment?

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