Chapter 18: Problem 67
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
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Chapter 18: Problem 67
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
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(a) Explain why the concentration of dissolved oxygen in freshwater is an important indicator of the quality of the water. (b) How is the solubility of oxygen in water affected by increasing temperature?
The degradation of \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{~F}\) (an HFC) by OH radicals in the troposphere is first order in each reactant and has a rate constant of \(k=1.6 \times 10^{8} \mathrm{M}^{-1} \mathrm{~s}^{-1}\) at \(4{ }^{\circ} \mathrm{C}\). If the tropo- spheric concentrations of \(\mathrm{OH}\) and \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{~F}\) are \(8.1 \times 10^{5}\) and \(6.3 \times 10^{8}\) molecules/cm \(^{3}\), respectively, what is the rate of reaction at this temperature in \(M / s ?\)
(a) Which of the following ionic species could be responsible for hardness in a water supply: \(\mathrm{Ca}^{2+}, \mathrm{K}^{+}, \mathrm{Mg}^{2+}, \mathrm{Fe}^{2+}, \mathrm{Na}^{+} ?\) (b) What properties of an ion determine whether it will contribute to water hardness?
As of the writing of this text, EPA standards limit atmospheric ozone levels in urban environments to 84 ppb. How many moles of ozone would there be in the air above Los Angeles County (area about 4000 square miles; consider a height of 10 \(\mathrm{m}\) above the ground) if ozone was at this concentration?
The organic anion is found in most detergents. Assume that the anion undergoes aerobic decomposition in the following manner: $$ \begin{array}{r} 2 \mathrm{C}_{18} \mathrm{H}_{29} \mathrm{SO}_{3}^{-}(a q)+51 \mathrm{O}_{2}(a q) \longrightarrow \\ 36 \mathrm{CO}_{2}(a q)+28 \mathrm{H}_{2} \mathrm{O}(l)+2 \mathrm{H}^{+}(a q)+2 \mathrm{SO}_{4}^{2-}(a q) \end{array} $$ What is the total mass of \(\mathrm{O}_{2}\) required to biodegrade \(10.0 \mathrm{~g}\) of this substance?
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