Chapter 18: Problem 6
Distinguish among salt water, freshwater, and groundwater. \([\) Section 18.3\(]\)
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Chapter 18: Problem 6
Distinguish among salt water, freshwater, and groundwater. \([\) Section 18.3\(]\)
These are the key concepts you need to understand to accurately answer the question.
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The average concentration of carbon monoxide in air in an Ohio city in 2006 was 3.5 ppm. Calculate the number of CO molecules in \(1.0 \mathrm{~L}\) of this air at a pressure of 759 torr and a temperature of \(22^{\circ} \mathrm{C}\).
The Henry's law constant for \(\mathrm{CO}_{2}\) in water at \(25^{\circ} \mathrm{C}\) $$ \text { is } 3.1 \times 10^{-2} M \mathrm{~atm}^{-1} $$ (a) What is the solubility of \(\mathrm{CO}_{2}\) in water at this temperature if the solution is in contact with air at normal atmospheric pressure? (b) Assume that all of this \(\mathrm{CO}_{2}\) is in the form of \(\mathrm{H}_{2} \mathrm{CO}_{3}\) produced by the reaction between \(\mathrm{CO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}:\) $$ \mathrm{CO}_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{CO}_{3}(a q) $$ What is the \(\mathrm{pH}\) of this solution?
Write balanced chemical equations for each of the following reactions: (a) The nitric oxide molecule undergoes photodissociation in the upper atmosphere. (b) The nitric oxide molecule undergoes photoionization in the upper atmosphere. (c) Nitric oxide undergoes oxidation by ozone in the stratosphere. (d) Nitrogen dioxide dissolves in water to form nitric acid and nitric oxide.
Bioremediation is the process by which bacteria repair their environment in response, for example, to an oil spill. The efficiency of bacteria for "eating" hydrocarbons depends on the amount of oxygen in the system, pH, temperature, and many other factors. In a certain oil spill, hydrocarbons from the oil disappeared with a first-order rate constant of \(2 \times 10^{-6} \mathrm{~s}^{-1}\). How many days did it take for the hydrocarbons to decrease to \(10 \%\) of their initial value?
The hydroxyl radical, \(\mathrm{OH}\), is formed at low altitudes via the reaction of excited oxygen atoms with water: $$ \mathrm{O}^{*}(g)+\mathrm{H}_{2} \mathrm{O}(g) \longrightarrow 2 \mathrm{OH}(g) $$ (a) Write the Lewis structure for the hydroxyl radical. (Hint: It has one unpaired electron.) Once produced, the hydroxyl radical is very reactive. Explain why each of the following series of reactions affects the pollution in the troposphere: (b) \(\mathrm{OH}+\mathrm{NO}_{2} \longrightarrow \mathrm{HNO}_{3}\) (c) \(\mathrm{OH}+\mathrm{CO}+\mathrm{O}_{2} \longrightarrow \mathrm{CO}_{2}+\mathrm{OOH}\) \(\mathrm{OOH}+\mathrm{NO} \longrightarrow \mathrm{OH}+\mathrm{NO}_{2}\) (d) \(\mathrm{OH}+\mathrm{CH}_{4} \longrightarrow \mathrm{H}_{2} \mathrm{O}+\mathrm{CH}_{3}\) \(\mathrm{CH}_{3}+\mathrm{O}_{2} \longrightarrow \mathrm{OOCH}_{3}\) \(\mathrm{OOCH}_{3}+\mathrm{NO} \longrightarrow \mathrm{OCH}_{3}+\mathrm{NO}_{2}\) (e) The concentration of hydroxyl radicals in the troposphere is approximately \(2 \times 10^{6}\) radicals per \(\mathrm{cm}^{3}\). This estimate is based on a method called long path absorption spectroscopy (LPAS), similar in principle to the Beer's law measurement discussed in the Closer Look essay on p. 564 , except that the path length in the LPAS measurement is \(20 \mathrm{~km}\). Why must the path length be so large?
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