Chapter 11: Problem 86
A watch with a liquid crystal display (LCD) does not function properly when it is exposed to low temperatures during a trip to Antarctica. Explain why the LCD might not function well at low temperature.
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Chapter 11: Problem 86
A watch with a liquid crystal display (LCD) does not function properly when it is exposed to low temperatures during a trip to Antarctica. Explain why the LCD might not function well at low temperature.
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The table shown here lists the molar heats of vaporization for several organic compounds. Use specific examples from this list to illustrate how the heat of vaporization varies with (a) molar mass, (b) molecular shape, (c) molecular polarity, (d) hydrogen-bonding interactions. Explain these comparisons in terms of the nature of the intermolecular forces at work. (You may find it helpful to draw out the structural formula for each compound.) $$ \begin{array}{ll} \text { Compound } & \begin{array}{l} \text { Heat of Vaporization } \\ \mathbf{( k J / m o l )} \end{array} \\ \hline \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{3} & 19.0 \\ \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3} & 27.6 \\ \mathrm{CH}_{3} \mathrm{CHBrCH}_{3} & 31.8 \\ \mathrm{CH}_{3} \mathrm{COCH}_{3} & 32.0 \\ \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{Br} & 33.6 \\ \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH} & 47.3 \end{array} $$
Name the phase transition in each of the following situations and indicate whether it is exothermic or endothermic: (a) Bromine vapor turns to bromine liquid as it is cooled. (b) Crystals of iodine disappear from an evaporating dish as they stand in a fume hood. (c) Rubbing alcohol in an open container slowly disappears. (d) Molten lava from a volcano turns into solid rock.
(a) Two pans of water are on different burners of a stove. One pan of water is boiling vigorously, while the other is boiling gently. What can be said about the temperature of the water in the two pans? (b) A large container of water and a small one are at the same temperature. What can be said about the relative vapor pressures of the water in the containers?
(a) How does the average kinetic energy of molecules compare with the average energy of attraction between molecules in solids, liquids, and gases? (b) Why does increasing the temperature cause a solid substance to change in succession from a solid to a liquid to a gas? (c) What happens to a gas if you put it under extremely high pressure?
Ethylene glycol \(\left(\mathrm{HOCH}_{2} \mathrm{CH}_{2} \mathrm{OH}\right)\) is the major component of antifreeze. It is a slightly viscous liquid, not very volatile at room temperature, with a boiling point of \(198^{\circ} \mathrm{C}\). Pentane \(\left(\mathrm{C}_{5} \mathrm{H}_{12}\right),\) which has about the same molecular weight, is a nonviscous liquid that is highly volatile at room temperature and whose boiling point is \(36.1^{\circ} \mathrm{C}\). Explain the differences in the physical properties of the two substances.
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