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When 0.963 g of glucose, C6H6, is burned in a bomb calorimeter, the temperature of the calorimeter increases by 8.39°C. The bomb has a heat capacity of 784 J/°C and is submerged in 925 mL of water. How much heat was produced by the combustion of the glucose sample?

Short Answer

Expert verified

Heat produced by combustion of glucose sample = -39.0 kJ.

Step by step solution

01

Formula

The heat which is produced by the combustion reaction is primarily absorbed by the water and the bomb calorimeter. This is shown by

\({{\bf{q}}_{{\bf{rxn}}}}{\bf{ = - (}}{{\bf{q}}_{{\bf{water}}}}{\bf{ + }}{{\bf{q}}_{{\bf{bomb}}}}{\bf{)}}\)

Density of water is 1.0 g/mL; so 925 ml water = 925 g water.

02

Calculation of heat

The known values are substituted in the above equation. We have

\(\begin{array}{c}{{\rm{q}}_{{\rm{rxn}}}}{\rm{ = - (}}{{\rm{q}}_{{\rm{water}}}}{\rm{ + }}{{\rm{q}}_{{\rm{bomb}}}}{\rm{)}}\\{\rm{ = - }}\left[ {\left( {{\rm{4}}{\rm{.184 J/g ^\circ C}}} \right){\rm{ \times }}\left( {{\rm{925 g}}} \right){\rm{ \times }}\left( {{\rm{8}}{\rm{.39 ^\circ C}}} \right){\rm{ + 784 J/^\circ C \times }}\left( {{\rm{8}}{\rm{.39 ^\circ C}}} \right)} \right]\\{\rm{ = - }}\left( {{\rm{32471 + 6577}}} \right)\\{\rm{ = - 39048 J\; = \; - 39}}{\rm{.0 kJ}}\end{array}\)

So, -39.0 kJ heat is produced by the combustion of 0.963 g of glucose.

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