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A mixture of \(0.200\;{\rm{g}}\) of \({{\rm{H}}_2},1.00\;{\rm{g}}\) of \({{\rm{N}}_2}\), and \(0.820\;{\rm{g}}\)of \({\rm{Ar}}\)is stored in a closed container at STP. Find the volume of the container, assuming that the gases exhibit ideal behaviour.

Short Answer

Expert verified

The volume of the container is 3.48 litres.

Step by step solution

01

Definition of volume

A substance's volume is the amount of space it occupies.

02

Converting gas into number of moles

Converting \(0.2\) grams of \({{\bf{H}}_2}\) gas into no. of moles of \({{\bf{H}}_2}\)gas.

Atomic weight of Hydrogen \((H) = 1\)grams.

So, molecular weight of \({{\rm{H}}_2} = (2) \cdot (1)\)grams.

\( = 2\)grams.

i.e. \(2\) grams of \({{\rm{H}}_2} = 1\) mole of \({{\rm{H}}_2}\).

So, no. of moles of gas of \({{\rm{H}}_2}\left( {{n_1}} \right) = \left( {0.2} \right.\) grams of \(\left. {{{\rm{H}}_2}} \right) \times \left( {\frac{{1{\rm{ mole }}}}{{2{\rm{ grams of }}{{\rm{H}}_2}}}} \right) = 0.1\) moles of \({{\rm{H}}_2}\).

Converting 1 grams of \({{\bf{N}}_2}\) gas into no. of moles of \({{\bf{N}}_2}\) gas.

Atomic weight of Nitrogen \((N) = 14\) grams.

So, molecular weight of \({{\rm{N}}_2} = (2) \cdot (14)\) grams.

\( = 28\)grams.

i.e. \(28\) grams of \( = {{\rm{N}}_2} = 1\) mole of \({{\rm{N}}_2}\).

So, no. of moles of gas of \({{\rm{N}}_2}\left( {{n_2}} \right) = \left( 1 \right.\) grams of \(\left. {{{\rm{N}}_2}} \right) \times \left( {\frac{{1{\rm{ mole }}}}{{28{\rm{ grams of }}{{\rm{N}}_2}}}} \right)\)

\( = 0.035\)moles of \({{\rm{N}}_2}\)

03

Find the volume of the container

Converting \(0.82\) grams of \(Ar\) gas into no. of moles of \(Ar\)gas.

Molecular weight of Argon \(({\rm{Ar}}) = 39.94\) grams.

i.e. \(39.94\) grams of \(Ar\)\( = 1\)mole of \(Ar\).

So, no. of moles of gas of \({\mathop{\rm Ar}\nolimits} \left( {{n_3}} \right) = (1\) grams of \({\rm{Ar}}) \times \left( {\frac{{1{\rm{ mole }}}}{{39.94{\rm{ grams of Ar}}}}} \right)\)

\( = 0.0205\)moles of \(Ar\).

Total no. of moles \( = (0.1) + (0.035) + (0.0205)\)moles. \( = 0.1555\) moles.

Under STP conditions, Volume occupied by \(1\) mole of gas \( = 22.4\)Liters.

Therefore, for \(0.1555\)moles, Volume occupied at \(STP\)condition is

\(\begin{aligned}{} &= (0.155) \cdot (22.4){\rm{ Liters}}{\rm{.}}\\ &= 3.48{\rm{ Liters}}{\rm{.}}\end{aligned}\)

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