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Why must the charge balance in oxidation-reduction reactions?

Short Answer

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The charge should be balanced in oxidation-reduction reactions because the number of electrons lost during oxidation is equal to the number of electrons gained during reduction.

Step by step solution

01

Define oxidation and reduction

  • The oxidation-reduction reaction is also known as a redox reaction. In this reaction, one reactant is oxidized and other is reduced. In balancing an oxidation-reduction reaction, they must be first divided into two half reactions: one is oxidation reaction and other is reduction reaction.
  • The balancing of redox reaction is complicated as compared to simple balancing. It is necessary to determine the half reactions of reactants undergoing oxidation and reduction. On adding the two halfreactions, net total equation can be obtained. This method of balancing redox reaction is known as half equation method.
02

Determine balanced reaction for each pair of half reactions in an acidic solution.

Because number of electrons lost during oxidation is equal to the number of electrons gained during reduction.In an oxidation-reduction reaction, one of the species oxidizes and the other reduces. Here, oxidation means loss of electrons and reduction means gain of electrons.The half- reaction method is used to balance the oxidation reduction reaction. In this method, first the unbalanced chemical reaction splits into two half reactions in which one is oxidation and other is reduction. The solutions in which the electrochemical reactions take place can be acidic, basic or neutral. The number of electrons lost by species undergoing reduction must be equal to the number of electrons gained by the species undergoing oxidation thus, the charge must be balanced.

The charge should be balanced in oxidation-reduction reactions because the number of electrons lost during oxidation is equal to the number of electrons gained during reduction.

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Most popular questions from this chapter

What mass of each product is produced in each of the electrolytic cells of the previous problem if a total charge of \({\bf{3}}.{\bf{33}} \times {\bf{1}}{{\bf{0}}^5}{\rm{ }}{\bf{C}}\) passes through each cell? Assume the voltage is sufficient to perform the reduction

What mass of zinc is required to galvanize the top of a 3.00 m × 5.50 m sheet of iron to a thickness of0.100 mm of zinc? If the zinc comes from a solution of \(Zn{\left( {N{O_3}} \right)_2}\) and the current is 25.5 A, how long will it take to galvanize the top of the iron? The density of zinc is 7.140 g/cm3

Consider the following metals: Ag, Au, \(Mg, Ni,\)\(and\)\(Zn\). Which of these metals could be used as a sacrificial anode in the cathodic protection of an underground steel storage tank? Steel is mostly iron, so use \( - 0.447\;{\rm{V}}\) as the standard reduction potential for steel.

If a sample of iron and a sample of zinc come into contact, the zinc corrodes but the iron does not. If a sample of iron comes into contact with a sample of copper, the iron corrodes but the copper does not. Explain this phenomenon.

The mass of three different metal electrodes, each from a different galvanic cell, were determined before andafter the current generated by the oxidation-reduction reaction in each cell was allowed to flow for a few minutes.The first metal electrode, given the label A, was found to have increased in mass; the second metal electrode, giventhe label B, did not change in mass; and the third metal electrode, given the label C, was found to have lost mass.

Make an educated guess as to which electrodes were active and which were inert electrodes, and which wereanode(s) and which were the cathode(s)

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