/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q4.122CP Use the oxidation number method ... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

Use the oxidation number method to balance the following equations by placing coefficients in the blanks. Identify the reducing and oxidizing agents:

(a)_KOH(aq)+_H2O2(aq)+_Cr(OH)3(s)→_K2CrO4(aq)+_H2O(l)(b)_MnO4−(aq)+_ClO2−(aq)+_H2O(l)→_MnO2(s)+_ClO4−(aq)+OH−(aq)(c)_KMnO4(aq)+_Na2SO3(aq)+_H2O(l)→_MnO2(s)+_Na2SO4(aq)+_KOH(aq)(d)_CrO42−(aq)+_HSnO2−(aq)+_H2O(l)→_CrO2−(aq)+_HSnO3−(aq)+OH−(aq)(e)_KMnO4(aq)+_NaNO2(aq)+_H2O(l)→_MnO2(s)+_NaNO3(aq)+_KOH(aq)(f)_I−(aq)+_O2(g)+_H2O(l)→_I2(s)+_OH−(aq)

Short Answer

Expert verified

The reactions are balanced by oxidation number method.

Step by step solution

01

Meaning of oxidation and reduction

Oxidation: In this process, electrons are lost by the element and the oxidation number of the element increases. The element that undergoes oxidation are called Reducing agent.

Reduction: In this process, the electrons are gained by the element and the oxidation number of the element decreases. The element that undergoes reduction are called Oxidising agent.

02

Reaction (a)

The oxidation state for each element present in the given reaction are shown below,

K+1O−2H+1(aq)+H+12O−12(aq)+Cr+3(OH)3(s)→K+12Cr+6O−64(aq)+H+12O−2(l)

From the reaction, it can be concluded that the oxidation state of chromium is increased from +3 to +6 and the oxidation state of oxygen is decreased from -1 to -2. Thus, the oxidising agent is H2O2 and the reducing agent is Cr(OH)3.

Now, the balanced equation for the given chemical reaction is,

4KOH(aq)+3H2O2(aq)+2Cr(OH)3(s)→2K2CrO4(aq)+8H2O(l)

03

Reaction (b)

The oxidation state for each element present in the given reaction are shown below,

Mn+7O−24−(aq)+Cl+3O−22−(aq)+H+12O−2(l)→Mn+4O−22(s)+Cl+7O−24−(aq)+O−2H+−(aq)

From the reaction, it can be concluded that the oxidation state of chlorine is increased from +3 to +7 and the oxidation state of manganese is decreased from +7 to +4. Thus, the oxidising agent is MnO4- and the reducing agent is ClO2-.

Now, the balanced equation for the given chemical reaction is,

4MnO4−(aq)+3ClO2−(aq)+2H2O(l)→4MnO2(s)+3ClO4−(aq)+4OH−(aq)

04

Reaction (c)

The oxidation state for each element present in the given reaction are shown below,

K+1Mn+7O−24(aq)+Na+12S+4O−23(aq)+H+12O−2(l)→Mn+4O−22(s)+Na+12S+6O−24(aq)+K+1O−2H+1(aq)

From the reaction, it can be concluded that the oxidation state of sulfur is increased from +4 to +6 and the oxidation state of manganese is decreased from +7 to +4. Thus, the oxidising agent is KMnO4 and the reducing agent is Na2SO4.

Now, the balanced equation for the given chemical reaction is,

2KMnO4(aq)+3Na2SO3(aq)+H2O(l)→2MnO2(s)+3Na2SO4(aq)+2KOH(aq)

05

Reaction (d)

The oxidation state for each element present in the given reaction are shown below,

Cr+6O−242−(aq)+H+1Sn+2O−22−(aq)+H+12O=2(l)→Cr+3O−22−(aq)+H+1Sn+4O−23−(aq)+O−2H+1−(aq)

From the reaction, it can be concluded that the oxidation state of Sn is increased from +2 to +4 and the oxidation state of chromium is decreased from +6 to +3. Thus, the oxidising agent is CrO42- and the reducing agent is HSnO2-.

Now, the balanced equation for the given chemical reaction is,

2CrO4−2(aq)+3HSnO2−(aq)+H2O(l)→2CrO2−(aq)+HSnO3−(aq)+2OH−(aq)

06

Reaction (e)

The oxidation state for each element present in the given reaction are shown below,

K+1Mn+7O−24(aq)+Na+1N+3O−22(aq)+H+12O−2(l)→Mn+4O−22(s)+Na+1N+5O−23(aq)+K+1O−2H+1(aq)

From the reaction, it can be concluded that the oxidation state of nitrogen is increased from +3 to +5 and the oxidation state of manganese is decreased from +7 to +4. Thus, the oxidising agent is KMnO4 and the reducing agent is NaNO2.

Now, the balanced equation for the given chemical reaction is,

2KMnO4(aq)+3NaNO2(aq)+H2O(l)→2MnO2(s)+3NaNO3(aq)+2KOH(aq)

07

Reaction (f)

The oxidation state for each element present in the given reaction are shown below,

I−1−(aq)+O02(g)+H+12O−2(l)→I02(s)+O−2H+1−(aq)

From the reaction, it can be concluded that the oxidation state of iodine is increased from -1 to 0 and the oxidation state of oxygen is decreased from 0 to -2. Thus, the oxidising agent is O2 and the reducing agent is I-.

Now, the balanced equation for the given chemical reaction is,

4I−(aq)+O2(g)+2H2O(l)→2I2(s)+4OH−(aq)

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Carbon dioxide is removed from the atmosphere of space capsules by reaction with a solid metal hydroxide. The products are water and the metal carbonate.

(a) Calculate the mass of CO2that can be removed by reaction with 3.50 kg of lithium hydroxide.

(b) How many grams of CO2 can be removed by 1.00 g of each of the following: lithium hydroxide, magnesium hydroxide, and aluminum hydroxide?

The net ionic equation for the aqueous neutralization reaction between acetic acid and sodium hydroxide is different from that for the reaction between hydrochloric acid and sodium hydroxide. Explain by writing balanced net ionic equations.

A chemist mixes solid AgCl, CuCl2, and MgCl2 in enough water to give a final volume of 50.0 mL.

(a) With ions shown as spheres and solvent molecules omitted for clarity, which of the following best represents the resulting mixture?

(b) If each sphere represents 5.0x10-3mol of ions, what is the total concentration of dissolved(separated) ions?

(c) What is the total mass of solid?

Sodium peroxide (Na2O2) is often used in self-contained breathing devices, such as those used in fire emergencies, because it reacts with exhaled CO2 to form Na2CO3 and O2. How many liters of respired air can react with 80.0 g of Na2O2 if each liter of respired air contains 0.0720 g of CO2?

To study a marine organism, a biologist prepares a 1.00-kg sample to simulate the ion concentrations in seawater. She mixes 26.5 g of NaCl, 2.40 g of MgCl2, 3.35 g of MgSO4, 1.20 g of CaCl2, 1.05 g of KCl, 0.315 g of NaHCO3, and 0.098 g of NaBr in distilled water.

(a) If the density of the solution is 1.025 g/cm3, what is the molarity of each ion?

(b) What is the total molarity of alkali metal ions?

(c) What is the total molarity of alkaline earth metal ions?

(d) What is the total molarity of anions?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.