Chapter 4: Q4.107 P (page 182)
Describe what happens on the molecular level when acetic acid dissolves in water.
Short Answer
You need to describe what happens on the molecular level when acetic acid dissolves in water.
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Chapter 4: Q4.107 P (page 182)
Describe what happens on the molecular level when acetic acid dissolves in water.
You need to describe what happens on the molecular level when acetic acid dissolves in water.
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Question: Over time, as their free fatty acid (FFA) content increases, edible fats and oils become rancid. To measure rancidity, the fat or oil is dissolved in ethanol, and any FFA present is titrated with KOH dissolved in ethanol. In a series of tests on olive oil, a stock solution of 0.050 M ethanolic KOH was prepared at 250C , stored at 0oC, and then placed in a 100-mL buret to titrate any oleic acid present in the oil. Each of four 10.00-g samples of oil took several minutes to titrate: the first required 19.60 mL, the second 19.80 mL, and the third and fourth 20.00 mL of the ethanolic KOH.
(a) What is the apparent acidity of each sample, in terms of mass % of oleic acid? (Note: As the ethanolic KOH warms in the buret, its volume increases by a factor of .)
(b) Is the variation in acidity a random or systematic error? Explain.
(c) What is the actual acidity? How would you demonstrate this?
Ammonia is produced by the millions of tons annually for use as a fertilizer. It is commonly made from N2 and H2 by the Haber process. Because the reaction reaches equilibrium before going completely to product, the stoichiometric amount of ammonia is not obtained. At a particular temperature and pressure, 10.0 g of H2 reacts with 20.0 g of N2 to form ammonia. When equilibrium is reached, 15.0 g of NH3 has formed.
(a) Calculate the percent yield.
(b) How many moles of N2 and H2 are present at equilibrium?
A person’s blood alcohol (C2H5OH) level can be determined by titrating a sample of blood plasma with a potassium dichromate solution. The balanced equation is
If 35.46mL of 0.05961M Cr2O72- is required to titrate 28.00 g of plasma, what is the mass percent of alcohol in the blood?
In a combination reaction, 1.62 g of lithium is mixed with 6.50 g of oxygen.
(a) Which reactant is present in excess?
(b) How many moles of product are formed?
(c) After reaction, how many grams of each reactant and product are present?
Limestone (CaCO3) is used to remove acidic pollutants from smokestack flue gases. It is heated to form lime (CaO), which reacts with sulfur dioxide to form calcium sulfite. Assuming a 70.% yield in the overall reaction, what mass of limestone is required to remove all the sulfur dioxide formed by the combustion of 8.5104 kg of coal that is 0.33 mass % sulfur?
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