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Sodium bromide dehydrate on strong heating loses 2 moles of water

$\mathbf{NaBr}\mathbf{.}\mathbf{2}{\mathbf{H}}_{\mathbf{2}}\mathbf{O}\stackrel{\mathbf{鈭�}}{\mathbf{鈫�}}\mathbf{NaBr}\mathbf{.}\mathbf{2}{\mathbf{H}}_{\mathbf{2}}\mathbf{O}$

Molar mass of NaBr.2H₂O = 138.922 g/mol

Molar mass of H₂O = 18.016 g/mol.

So, 138.922 g of NaBr.2H₂O loses 36.032 g of water.

Similarly, Magnesium bromide dehydrate on strong heating loses 6 moles of water

${\mathbf{MgBr}}_{\mathbf{2}}\mathbf{.}\mathbf{6}{\mathbf{H}}_{\mathbf{2}}\mathbf{O}\stackrel{\mathbf{鈭�}}{\mathbf{鈫�}}{\mathbf{MgBr}}_{\mathbf{2}}\mathbf{+}\mathbf{6}{\mathbf{H}}_{\mathbf{2}}\mathbf{O}$

Molar mass of MgBr₂.6H₂O = 292.206 g/mol

Molar mass of H₂O = 18.016 g/mol.

So, 138.922 g of MgBr₂.6H₂O loses 108.096 g of water.

Total mass of the mixture is,

$\mathbf{138}\mathbf{脳}\mathbf{922}\mathbf{g}\mathbf{+}\mathbf{292}\mathbf{.}\mathbf{206}\mathbf{g}\mathbf{=}\mathbf{431}\mathbf{.}\mathbf{128}\mathbf{g}$

Total mass of water lost is,

$\mathbf{36}\mathbf{.}\mathbf{02}\mathbf{g}\mathbf{+}\mathbf{108}\mathbf{.}\mathbf{096}\mathbf{g}\mathbf{=}\mathbf{144}\mathbf{.}\mathbf{128}\mathbf{g}$

Actual mass of water lost = 252.1 mg = 0.2521 g

Mass of the mixture that loses 0.2521 g is,

$\mathbf{0}\mathbf{.}\mathbf{2521}{\mathbf{gH}}_{\mathbf{2}}\mathbf{O}\mathbf{脳}\frac{\mathbf{431}\mathbf{.}\mathbf{128}\mathbf{g}}{\mathbf{144}\mathbf{.}\mathbf{128}\mathbf{g}}\mathbf{=}\mathbf{0}\mathbf{.}\mathbf{7541}\mathbf{g}$

Mass of NaBr.2H₂O present in 0.7541 g mixture is,

$$\begin{gathered} =\mathbf{0}\mathbf{.}\mathbf{7541}\mathbf{g}\mathbf{脳}\frac{\mathbf{138}\mathbf{.}\mathbf{922}\mathbf{g}}{\mathbf{431}\mathbf{.}\mathbf{128}\mathbf{gmixture}} \\ \mathbf{=}\mathbf{0}\mathbf{.}\mathbf{2430}\mathit{g} \end{gathered}$$

Mass percent of NaBr.2H₂O is,

$$\begin{gathered} \mathbf{=}\frac{\mathbf{mass}}{\mathbf{totalmass}}\mathbf{脳}\mathbf{100}\mathbf{\%} \\ \mathbf{=}\frac{\mathbf{0}\mathbf{.}\mathbf{2430}\mathbf{g}}{\mathbf{0}\mathbf{.}\mathbf{7541}\mathbf{g}}\mathbf{脳}\mathbf{100}\mathbf{\%} \\ \mathbf{=}\mathbf{32}\mathbf{.}\mathbf{22}\mathbf{\%} \end{gathered}$$

Mass percent of MgBr₂.6H₂O is,

=100%-32.22%

=67.78%

Hence, the mass % of NaBr.2H₂Oand MgBr₂.6H₂O are 32.22% and 67.78%, respectively.