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Chapter 2: The Components of Matter

Q15.95 P

Page 40

Draw the R group of (a) glycine; (b) isoleucine; (c) tyrosine.

Q15.98 P

Page 40

Write the sequence of the complementary DNA strand that pairs with each of the following DNA base sequences:

(a) TTAGCC

(b) AGACAT

Q15.99 P

Page 40

Question: Write the sequence of the complementary DNA strand that pairs with each of the following DNA base sequences:

(a) GGTTAC

(b) CCCGAA

Q15P

Page 81

Which of the following scenes illustrate(s) the fact that compounds of chlorine (green) and oxygen (red) exhibit the law of multiple proportions? Name the compounds.

Q160CP

Page 40

Liquid ammonia auto ionizes like water:

2NH3(l)NH4+(am) + NH2-(am)

where (am) represents solvation byNH3.

(a) Write the ion-product constant expression, Kam.

b) What are the strongest acid and base that can exist inNH3(l)?

(c)HNO3and HCOOH are levelled inNH3(l). Explain with equations.

(d) At the boiling point(-33C),Kam=5.1脳10-27. Calculate [NH4+] at this temperature.

(e) Pure sulfuric acid also auto ionizes. Write the ion-product constant expression,Ksulf, and 铿乶d the concentration of the conjugate base at20C(Ksutf=2.7脳10-4补迟20掳颁)

Q162CP

Page 40

Thiamine hydrochloride (C12H18ON4SCl2)is a water soluble form of thiamine (vitamin B1; Ka= 3.3710- 7. How many grams of the hydrochloride must be dissolved in 10.00mL of water to give a pH of 3.50?

Q167CP

Page 40

At 50Cand 1 atm,Kw= 5.1910- 14. At these conditions, 铿乶d

(a)[H3O+]in pure water,

(b)[H3O+]in 0.010 MNaOH , and

(c) [OH] in0.0010MHClO4.

(d) Find[H3O+]in 0.0100 MKOH at100Cand 1000atm (Kw = 1.101012).

(e) Find the pH of pure water at100Cand 1000atm

Q16P

Page 81

(a) Does the percent by mass of each element in a compound depend on the amount of compound? Explain.

(b) Does the mass of each element in a compound depend on the amount of compound? Explain.

Q171CP

Page 40

The Group 5A(15)hydrides react with boron trihalides in a reversible Lewis acid-base reaction. When 0.15mol ofPH3BCl3 (s) is introduced into a3.0 -Container at a certain temperature,8.410- 3mol ofPH3is present at equilibrium:

PH3BCl3(s)PH3(g) + BCl3(g)

(a) FindKcfor the reaction at this temperature.

(b) Draw a Lewis structure for the reactant

Q172CP

Page 40

A 1000m solution of chloroacetic acid(ClCH2COOH)freezes at 1.93C. Find the Ka of chloroacetic acid. (Assume the molarities equal the molalities.)

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