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Chapter 14: Q102P (page 623)

Use the VSEPR model to predict the structure of the cyclic ion P3O93-

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01

VSEPR Theory

VSEPR theory is the short form for the valence shell electron pair repulsion theory. It can be used to denote the structure of the compounds. To use it, identify the central atom in each compound and the valence electrons on it. The lone pair and bond pair repulsions are considered in determining the structure.

02

The structure of the compound is shown below.

The structure of the compound is shown below.

The central atom is considered as phosphorus, P. The number of electrons in the valence shell is used for the bond formation. The bonding is satisfied for both phosphorus and oxygen atoms.

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Most popular questions from this chapter

Bromine monofluoride (BF) disproportionates to bromine gas and bromine tri- and pentafluorides. Use the following to find 螖Horxnfor the decomposition of BrF to its elements:

3BrF(g)鈫�Br2(g)+BrF3(l)螖Horxn=-125.3KJ\hfill5BrF(g)鈫�2Br2(g)+BrF5(l)螖Horxn=-166.1KJ\hfillBrF3(l)+F2鈫�(g)BrF5(l)螖Horxn=-158.0KJ\hfill

Thallium forms the compound TlI3. What is the apparent oxidation state of Tl in this compound? Given that the anion is I3-, what is the actual oxidation state of Tl? Draw the shape of the anion, giving its VSEPR class and bond angles. Propose a reason why the compound does not exist as(Tl3+)(I-)3.

Rank the following in order of decreasing

(a) Boiling point: O2, Br2, As(s)

(b)螖贬vap: Cl2, Ar, I2

Even though EN values vary relatively little down a group 4A (14), the elements change from nonmetal to metal. Explain.

Which member of each pair has more ioniccharacter in its bonds:

(a) BeF2 or CaF2; (b) PbF2 or PbF4; (c) GeF4 or PF3?
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