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The reaction that allows for radiocarbon dating is the continual formation of carbon-14 in the upper atmosphere:

N714+01n→614C+11H

What is the energy change associated with this process in eV/reaction and in kJ/mol reaction? (Masses of atoms:N714=14.003074amu;C614=14.003241amu;H11=1.007825 amu; n01=1.008665amu.)

Short Answer

Expert verified

Energy=60478572.64kmol

Step by step solution

01

Definition of Continual formation

The carbon cycle depicts the continuous movement of carbon atoms from the atmosphere to the Earth and back to the atmosphere. The amount of carbon in this system does not fluctuate because our planet and its atmosphere are a closed system. The location of carbon in the atmosphere and on Earth is continually changing.

02

Find the energy change associated with this process

We find the mass that is equivalent to this energy from Einstein's equation:

E = mc2

where 4m is the mass difference between reactants and products:

4m=mproducts-mreactants

4m=(14.003074+1.008665)-(14.003241+1.007825)

4m=0.000673amu

Binding energies are commonly expressed in millions of electron volts, that is, in mega-electron volts (MeV):

1MeV=106eV=1.602x10-13J

A particularly useful factor converts the atomic mass unit to its energy equivalent in electron volts:

1amu=931.5x106eV=931.5MeVEnergy=0.000673amu931.5MeV1amu106eV1MeV=6.2690x105eVEnergy=6.2690x105eV1.602x10-19J1eV1kJ1000J6.022x10231molEnergy=60478572.64kmol

Thus,Energy=60478572.64kmol

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Most popular questions from this chapter

Technetium-99m is a metastable nuclide used in numerous cancer diagnostic and treatment programs. It is prepared just before use because it decays rapidly through y emission:

T99m→99Tc+γ

Use the data below to determine

(a) The half-life of T99mc;

(b) The percentage of the isotope that is lost if it takes 2.0 h to prepare and administer the dose.

Time(h)

y emission (photons / s)

0

5000

4

3150

8

2000

12

1250

16

788

20

495

Question: Uranium and radium are found in many rocky soils throughout the world. Both undergo radioactive decay, and one of the products is radon-222, the heaviest noble gas (t=3.82 days). Inhalation of this gas contributes to many lung cancers. According to Environmental Protection Agency recommendations, the level of radioactivity from radon in homes should not exceed 4.0 p Ci/L of air.

(a) What is the safe level of radon in Bq/L of air?

(b) A home has a radon measurement of 41.5 pCi/L. The owner vents the basement in such a way that no more radon enters the living area. What is the activity of the radon remaining in the room air (in Bq/L) after 9.5 days

(c) How many more days does it take to reach the EPA recommended level?

Tritium H3;t1/2=12.26yr is continually formed in the upper troposphere by interaction of solar particles with nitrogen. As a result, natural waters contain a small amount of tritium. Two samples of wine are analyzed, one known to be made in 1941 and another made earlier. The water in the 1941 wine has 2.23 times as much tritium as the water in the other. When was the other wine produced?

The reaction that will probably power the first commercial fusion reactor is

H +1213H→24He +01n

How much energy would be produced per mole of reaction?

(Masses of atoms: H = 3.01605amu;1213H = 2.0140amu;

He = 4.00260amu;mass of0124n = 1.008665amu.)

Question:N237pis the parent nuclide of a decay series that starts with α-emission, followed by β-emission, and then two more emissions. Write a balanced nuclear equation for each step?

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