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What is the component concentration ratio, [BrO-]/[HBrO],of a buffer that has a pH of7.95(KaofHBrO=2.3×10-9)?

Short Answer

Expert verified

The component concentration ratio obtained is [BrO-][HBrO]= 0.20

Step by step solution

01

Buffer solution

A buffer solution withstands the change in a pH value. An acidic buffer is formed by combining a weak acid and the salt of its conjugate base.

02

Evaluate the component concentration ratio

Write theHBrOdissociation reaction first.

HBrO +H2O⇌H3O++ BrO-.

We must alter the Henderson-Hasselbalch equation to find[BrO-][HBrO].

The pH andKaare known. Therefore, first solve for thepKa.

pKa= - logKa= - log(2.3×10-9)=8.64

Then, solve for[BrO-][HBrO]using the Henderson-Hasselbalch equation as:

pH = pKa+ log[BrO-][HBrO]log[BrO-][HBrO]= pH - pKa[BrO-][HBrO]= 10pH - pKa= 107.95 - 8.64= 0.20.

Therefore, thecomponent concentration ratio obtained is[BrO-][HBrO]= 0.20.

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