91Ó°ÊÓ

In polar liquids, the ionic material dissociates into its ions in ionic equilibrium. The ions generated in the solution are always in equilibrium with the undissociated solute.

Simplify the given values:

$\begin{array}{c}\text{m}\left({\text{ZnCl}}_{\text{2}}\right)\text{=0.84gV(NaCN)}\\ \text{=245ml}\\ \text{=0.245lc(NaCN)}\\ \text{=0.150M}\end{array}$

We can start by writing the formation equation for:${\text{Zn(CN)}}_{\text{4}}^{\text{2-}}$

$\begin{array}{l}{\text{Zn}}^{\text{2+}}{\text{+4CN}}^{\text{-}}⇌{\text{Zn(CN)}}_{\text{4}}^{\text{2-}}\\ \text{Kf=}\frac{\left[{\text{Zn(CN)}}_{\text{4}}^{\text{2-}}\right]}{\left[{\text{Zn}}^{\text{2+}}\right]\text{×}{\left[{\text{CN}}^{\text{-}}\right]}^{\text{4}}}{\text{=4.2×10}}^{\text{19}}\end{array}$

Now, we can calculate$\left[{\text{Zn}}^{\text{2+}}\right]$ :

$\begin{array}{c}\text{n}\left({\text{Zn}}^{\text{2+}}\right)\text{=}\frac{{\text{0.84gZnCl}}_{\text{2}}}{{\text{136.286g/molZnCl}}_{\text{2}}}\\ \text{=0.0061mol}\\ \left[{\text{Zn}}^{\text{2+}}\right]\text{=}\frac{\text{0.0061mol}}{\text{0.245l}}\\ \text{=0.02516M-x}\end{array}$

We put "- x" because some of the${\text{Zn}}^{\text{2+}}$ will be consumed during the reaction

Now we can do the same for $\left[{\text{CN}}^{\text{-}}\right]$:

$\left[{\text{CN}}^{\text{-}}\right]\text{=0.150M-4x}$

We put " -4x " because for every${\text{Zn}}^{\text{2+}}$ we need .

And now we do the same for :$\left[{\text{Zn(CN)}}_{\text{4}}^{\text{2-}}\right]$

$\left[{\text{Zn(CN)}}_{\text{4}}^{\text{2-}}\right]\text{=x}$

We must now suppose that all of the initial $\left[{\text{Zn}}^{\text{2+}}\right]$ has completely reacted, resulting in a concentration of the produced ${\text{Zn(CN)}}_{\text{4}}^{\text{2-}}$ be $\text{0.02516M}$and that is " x " value.

$\left[{\text{Zn(CN)}}_{\text{4}}^{\text{2-}}\right]\text{=0.02516M}$

Now that we have our " x " value we can calculate :$\left[{\text{CN}}^{\text{-}}\right]$

$\begin{array}{c}\left[{\text{CN}}^{\text{-}}\right]\text{=0.150²Ñ-4×0.02516²Ñ}\\ \text{=0.0494M}\end{array}$

Now we have to use the Kf expression to calculate $\left[{\text{Zn}}^{\text{2+}}\right]$ :

$\begin{array}{c}\left[{\text{Zn}}^{\text{2+}}\right]\text{=}\frac{\left[{\text{Zn(CN)}}_{\text{4}}^{\text{2-}}\right]}{\text{°­´Ú×}{\left[{\text{CN}}^{\text{-}}\right]}^{\text{4}}}\\ {\text{=1.01×10}}^{\text{-16}}\text{M}\end{array}$

Therefore, the values are

$\begin{array}{c}\left[{\text{Zn(CN)}}_{\text{4}}^{\text{2-}}\right]\text{=0.02516M}\\ \left[{\text{CN}}^{\text{-}}\right]\text{=0.150²Ñ-4×0.02516²Ñ}\\ \text{=0.0494M}\\ \left[{\text{Zn}}^{\text{2+}}\right]\text{=}\frac{\left[{\text{Zn(CN)}}_{\text{4}}^{\text{2-}}\right]}{\text{°­´Ú×}{\left[{\text{CN}}^{\text{-}}\right]}^{\text{4}}}\\ {\text{=1.01×10}}^{\text{-16}}\text{M}\end{array}$