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Sulfur dioxide is produced in enormous amounts for sulfuric acid production. It melts at -73oCand boils at-10oC . Its Δ±áofusis 8.619 kJ/mol and itsis 25.73 kJ/mol. The specific heat capacities of the liquid and gas are 0.995 J/gK and 0.622 J/gK, respectively. How much heat is required to convert 2.500 kg of solid role="math" localid="1656937400249" SO2at the melting point to a gas at60oC ?

Short Answer

Expert verified

The total heat required to convert 2500gram of solid SO2to vapour phase SO2 at the melting point of the gas at 60oCis 1605812.5Joule.

Step by step solution

01

Enthalpy of Vaporization 

The phase diagram is the diagram which shows thechange in phase. It tells about the change into all phases – Solid, Liquid and Gaseous.

It represents all the phases and transition are shown by the lines and the area between lines show the whole phase of the molecule.

02

Numerical Explanation 

Molar Mass of =64g/mole

Boiling Point = -10oC

Melting Point = -73oC

ΔHofus=8.619kJ/moleChangeJ/moletoJ/g⇒ΔHofus=8.619kJ/mole×1mole64g×1000J/kJ⇒ΔHofus=134.5J/gΔHovap=25.73kJ/mole⇒ΔHovap=25.73kJ/mole×1mole64g×1000J/kJ⇒ΔHovap=401.6J/g

Specific Heat Capacity of liquid,Cliq=0.995kJ/mole

Specific Heat Capacity of Gas,Cgas=0.622kJ/mole

Mass of SO2= 2.5kg = 2500g

Convert 2.5kg Solid SO2 to liquid SO2Specific Heat Cpacity,q=m ΔHofus⇒q=(2500 g)×(134.5 J/g)⇒q=336250 J

Convert 2.5kg liquid SO2 from-73oC to-10oCSpecific Heat Cpacity,q=mCliq ΔTΔT=(-10oC)-(-73oC)=63oC⇒q=2500g×0.995×63oC⇒q=156712.5 J

Convert 2.5kg liquid SO2 into Vapours from-10oC to-10oCSpecific Heat Capacity,q=m ΔHovap⇒q=2500 g×401.6 J/g⇒q=1004000J

Convert 2.5kg Gaseous SO2 from-10oC to 60oCSpecific Heat Capacity,q=MCgas ΔTΔT=(60oC)-(-10oC)=70oC⇒q=2500g×0.622j/gk×70oC⇒q=108850J

The total heat energy required to convert solid into vapours.

Total Energy=(336250+156712.5+1004000+108850)qTotal=1605812.5J

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