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Predict the effect of increasing the temperature on the amounts of products in the following reactions:

(a)CO(g)+2H2(g)CH3翱贬(驳)鈥兾敱rxn=-90.7kJ

(b)C(s)+H2O(g)CO(g)+H2(驳)鈥兾敱ran=131kJ

(c) 2NO2(g)2NO(g)+O2(g)(endothermic)

(d) 2C(s)+O2(g)2CO(g)(exothermic)

Short Answer

Expert verified

Answer

(a) The amount of product available decreases.

(b) The amount of product produced increases.

(c) The amount of product produced increases.

(d) The amount of product available decreases.

Step by step solution

01

Definition of Concept

Reactions: A balanced chemical reaction equation shows the mole relationships of reactants and products, while a chemical reaction equation gives the reactants and products. The amount of energy involved in the reaction is frequently stated. Reaction stoichiometry is the study of the quantitative aspects of chemical reactions.

02

Predict the effect of increasing the temperature on the amounts of products

(a)

Considering the given reaction,

CO(g)+2H2(g)CH3翱贬(驳)鈥兾敱rxn=-90.7kJ

This is an exothermic reaction.

The equilibrium shifts to the left, bringing the reactants closer together.

Therefore, the amount of product available decreases.

03

Predict the effect of increasing the temperature on the amounts of products

(b)

Considering the given reaction,

C(s)+H2O(g)CO(g)+H2(驳)鈥兾敱ran=131kJ

This is an endothermic reaction.

The balance shifts to the right, in favour of the products.

Therefore, the amount of product produced increases.

04

Predict the effect of increasing the temperature on the amounts of products

(c)

Considering the given reaction,

2NO2(g)2NO(g)O2(g)(endothermic)

This is an endothermic reaction.

The balance shifts to the right, in favour of the products.

Therefore, the amount of product produced increases.

05

Predict the effect of increasing the temperature on the amounts of products

(d)

Considering the given reaction,

2C(s)+O2(g)2CO(g)(endothermic)

This is an exothermic reaction.

The equilibrium shifts to the left, bringing the reactants closer together.

Therefore, the amount of product available decreases.

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Most popular questions from this chapter

Consider the formation of ammonia in two experiments.

  1. To a 1.00-L container at727oC1.30mol of N2and 1.65molofH2are added. At equilibrium, 0.100molofNH3 is present. Calculate the equilibrium concentrations of N2andH2, and find Kcfor the reaction: 2NH3(g)N2(g)+3H2(g)
  2. In a different 1.00-L container at the same temperature, equilibrium is established with 8.3410-2molofNH3,1.50molofN2,and1.25molofH2 present. CalculateKc for the reaction:NH3(g)N2(g)+32H2(g)
  3. (c) What is the relationship between the Kc values in parts (a) and (b) ? Why aren't these values the same?

Hydrogenation of carbon-carbon bonds is important in the petroleum and food industries. The conversion of acetylene to ethylene is a simple example of the process:

C2H2(g)+H2(g)C2H4(g)

The calculatedKc at 2000K is2.9108 . But the process is run at lower temperatures with the aid of a catalyst to prevent decomposition. Use螖贬f values to calculate theKC at 300K.

The powerful chlorinating agent sulfuryl dichloride (SO2Cl2)can be prepared by the following two-step sequence:

H2S(g)+O2(g)H2O(g)+SO2(g)

SO2(g)+Cl2(g)SO2Cl2(g)

  1. Balance each step, and write the overall equation.
  2. Show that the overallQcequals the product of theQc's for the individual steps.

When ammonia is made industrially, the mixture of N2,H2, anddata-custom-editor="chemistry" NH3 that emerges from the reaction chamber is far from equilibrium. Why does the plant supervisor use reaction conditions that produce less than the maximum yield of ammonia?

Balance each reaction and write its reaction quotient, Qc:

(a)NO(g)+O2(g)饾啅N2O3(g)(b)SF6(g)+SO3(g)饾啅SO2F2(g)(c)SCIF5(g)+H2(g)饾啅S2F10(g)+HCI(g)

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