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Use Appendix to calculate the percent dissociation of 0.55M benzoic acid, C6H5COOH.

Short Answer

Expert verified

The %dissociation=1.07%.

Step by step solution

01

Define dissociation

In chemistry, dissociation is the breaking up of a chemical into simpler elements that may normally recombine under different conditions. The addition of a solvent or energy in the form of heat causes molecules or crystals of a substance to break up into ions in electrolytic, or ionic, dissociation (electrically charged particles).

02

Explanation

For the dissociation of C6H5COOH, write the reaction equation.

C6H5COOH+H2OH3O++C6H5COO-

After that, create the ICE table to get the Kaequation.

[C6H5COOH]+H2OH3O++C6H5COO-I0.55M00C-x+x+xE0.55M-x+x+x

Ka=H3O+C6H5COO-[C6H5COOH]Ka=x20.55-x

As x=H3O+=C6H5COO-is well-known. As C6H5COOH is a weak acid, its Kavalue is quite low. Assume that the has no effect on the denominator's 0.55M.

Then, to solve for x, substitute the Ka.

Ka=x20.55x2=Ka(0.55)x=Ka(0.55)=6.3脳10-5(0.55)虫=5.89脳10-3M

We already know that x=H3O+. The percent dissociation may now be calculated.

%dissociation=xC6H5COOH脳100%=5.89脳10-30.55脳100%%dissociation=1.07%

Therefore, the percent dissociation is 1.07%.

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Most popular questions from this chapter

The following scenes represent three weak acids HA

(a) Rank the acids in order of increasing Ka.

(b) Rank the acids in order of increasingpKa.

c) Rank the conjugate bases in order of increasing pKb.

(d) What is the percent dissociation of HX?

(e) If equimolar amounts of the sodium salts of the acids (NaX, NaY, and NaZ) were dissolved in water, which solution would have the highest pOH? The lowest pH?

Explain the differing extents of dissociation of H2SO4in CH3COOH,H2O,and NH3.

(a) A Br酶nsted-Lowry acid-base reaction proceeds in the net direction in which a stronger acid and stronger base form a weaker acid and weaker base. Explain

(b) The molecular scene at the right depicts an aqueous solution of two conjugate acid-base pairs: HA/A and HB/B. The base in the first pair is represented by red spheres and the base in the second pair by green spheres; solvent molecules are omitted for clarity. Which is the stronger acid? Stronger base? Explain.

Question: Use Appendix C to rank the following in order of increasing acid strength: HIO3, HI, CH3COOH, HF .

Nitrogen is discharged from wastewater treatment facilities into rivers and streams, usually as NH3and role="math" localid="1663321622328" NH4:
role="math" localid="1663321638309" NH3(aq) +H2O(l)NH4+(aq) + OH-(aq)Kb= 1.76脳10- 5

One strategy for removing it is to raise the pH and 鈥渟trip鈥 the role="math" localid="1663321651423" NH3from solution by bubbling air through the water.

(a) At pH=7.00, what fraction of the total nitrogen in solution isrole="math" localid="1663321664485" NH3, de铿乶ed asrole="math" localid="1663321682077" [NH3]/(NH3+NH4+)

(b) What is the fraction at pH 10.00?

(c) Explain the basis of ammonia stripping.

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