Chapter 8: Problem 87
Although \(\mathrm{I}_{3}^{-}\) is known, \(\mathrm{F}_{3}^{-}\) is not. Using Lewis structures, explain why \(\mathrm{F}_{3}^{-}\) does not form.
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Chapter 8: Problem 87
Although \(\mathrm{I}_{3}^{-}\) is known, \(\mathrm{F}_{3}^{-}\) is not. Using Lewis structures, explain why \(\mathrm{F}_{3}^{-}\) does not form.
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(a) Describe the molecule chlorine dioxide, \(\mathrm{ClO}_{2}\), using three possible resonance structures. (b) Do any of these resonance structures satisfy the octet rule for every atom in the molecule? Why or why not? (c) Using formal charges, select the resonance structure(s) that is (are) most important.
(a) What are valence electrons? (b) How many valence electrons does a nitrogen atom possess? (c) An atom has the electron configuration \(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{2} .\) How many valence electrons does the atom have?
(a) Triazine, \(\mathrm{C}_{3} \mathrm{H}_{3} \mathrm{~N}_{3}\), is like benzene except that in triazine every other \(C-H\) group is replaced by a nitrogen atom. Draw the Lewis structure(s) for the triazine molecule. (b) Estimate the carbon-nitrogen bond distances in the ring.
The reaction of indium, In, with sulfur leads to three binary compounds, which we will assume to be purely ionic. The three compounds have the following properties: $$ \begin{array}{lll} \hline \text { Compound } & \text { Mass \% In } & \text { Melting Point }\left({ }^{\circ} \mathrm{C}\right) \\ \hline \text { A } & 87.7 & 653 \\ \text { B } & 78.2 & 692 \\ \text { C } & 70.5 & 1050 \\ \hline \end{array} $$ (a) Determine the empirical formulas of compounds A, B, and C. (b) Give the oxidation state of In in each of the three compounds. (c) Write the electron configuration for the In ion in each compound. Do any of these configurations correspond to a noble-gas configuration? (d) In which compound is the ionic radius of In expected to be smallest? Explain. (e) The melting point of ionic compounds often correlates with the lattice energy. Explain the trends in the melting points of compounds A, B, and \(\mathrm{C}\) in these terms.
Which of the following bonds are polar: (a) \(\mathrm{B}-\mathrm{F}\), (b) \(\mathrm{Cl}-\mathrm{Cl}\), (c) \(\mathrm{Se}-\mathrm{O}\), (d) \(\mathrm{H}-\mathrm{I}\) ? Which is the more electronegative atom in each polar bond?
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