Chapter 8: Problem 7
(a) What are valence electrons? (b) How many valence electrons does a nitrogen atom possess? (c) An atom has the electron configuration \(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{2} .\) How many valence electrons does the atom have?
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Chapter 8: Problem 7
(a) What are valence electrons? (b) How many valence electrons does a nitrogen atom possess? (c) An atom has the electron configuration \(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{2} .\) How many valence electrons does the atom have?
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(a) What is meant by the term covalent bond? (b) Give three examples of covalent bonding. (c) A substance \(X Y\), formed from two different elements, boils at \(-33^{\circ} \mathrm{C}\). Is XY likely to be a covalent or an ionic substance? Explain.
Which of the following molecules or ions contain polar bonds: (a) \(\mathrm{P}_{4}\), (b) \(\mathrm{H}_{2} \mathrm{~S}\), (c) \(\mathrm{NO}_{2}^{-}\), (d) \(\mathrm{S}_{2}{ }^{2-}\) ?
Consider benzene \(\left(\mathrm{C}_{6} \mathrm{H}_{6}\right)\) in the gas phase. (a) Write the reaction for breaking all the bonds in \(\mathrm{C}_{6} \mathrm{H}_{6}(g)\), and use data in Appendix \(C\) to determine the enthalpy change for this reaction. (b) Write a reaction that corresponds to breaking all the carbon-carbon bonds in \(\mathrm{C}_{6} \mathrm{H}_{6}(g) .\) (c) By combining your answers to parts (a) and (b) and using the average bond enthalpy for \(C-H\) from Table \(8.4\), calculate the average bond enthalpy for the carbon-carbon bonds in \(\mathrm{C}_{6} \mathrm{H}_{6}(\mathrm{~g}) .\) (d) Comment on your answer from part (c) as compared to the values for \(C-C\) single bonds and \(C=C\) double bonds in Table \(8.4 .\)
The iodine monobromide molecule, IBr, has a bond length of \(2.49 \AA\) and a dipole moment of \(1.21 \mathrm{D}\). (a) Which atom of the molecule is expected to have a negative charge? Explain. (b) Calculate the effective charges on the I and Br atoms in IBr, in units of the electronic charge \(e\).
Write Lewis structures that obey the octet rule for each of the following, and assign oxidation numbers and formal charges to each atom: (a) \(\mathrm{NO}^{+}\), (b) \(\mathrm{POCl}_{3}\) (P is bonded to the three \(\mathrm{Cl}\) atoms and to the \(\mathrm{O}\) ), (c) \(\mathrm{ClO}_{4}^{-}\), (d) \(\mathrm{HClO}_{3}(\mathrm{H}\) is bonded to \(\mathrm{O})\).
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