Chapter 7: Problem 96
Use orbital diagrams to illustrate what happens when an oxygen atom gains two electrons. Why is it extremely difficult to add a third electron to the atom?
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Chapter 7: Problem 96
Use orbital diagrams to illustrate what happens when an oxygen atom gains two electrons. Why is it extremely difficult to add a third electron to the atom?
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We can draw an analogy between the attraction of an electron to a nucleus and seeing a lightbulb-in essence, the more nuclear charge the electron "sees," the greater the attraction. (a) Within this analogy, discuss how the shielding by core electrons is analogous to putting a frosted-glass lampshade between the lightbulb and your eyes, as shown in the illustration. (b) Explain how we could mimic moving to the right in a row of the periodic table by changing the wattage of the lightbulb. (c) How would you change the wattage of the bulb and/or the frosted glass to mimic the effect of moving down a column of the periodic table? [Section 7.2]
Make a simple sketch of the shape of the main part of the periodic table, as shown (a) Ignoring \(\mathrm{H}\) and \(\mathrm{He}\), write a single straight arrow from the element with the smallest bonding atomic radius to the element with the largest. (b) Ignoring \(\mathrm{H}\) and \(\mathrm{He}\), write a single straight arrow from the element with the smallest first ionization energy to the element with the largest. (c) What significant observation can you make from the arrows you drew in parts (a) and (b)? [Sections \(7.3\) and 7.4]
(a) Why is cesium more reactive toward water than is lithium? (b) One of the alkali metals reacts with oxygen to form a solid white substance. When this substance is dissolved in water, the solution gives a positive test for hydrogen peroxide, \(\mathrm{H}_{2} \mathrm{O}_{2}\). When the solution is tested in a burner flame, a lilac-purple flame is produced. What is the likely identity of the metal? (c) Write a balanced chemical equation for reaction of the white substance with water.
It is possible to produce compounds of the form \(\mathrm{GeClH}_{3}, \mathrm{GeCl}_{2} \mathrm{H}_{2}\), and \(\mathrm{GeCl}_{3} \mathrm{H}\). What values do you predict for the Ge \(-\mathrm{H}\) and \(\mathrm{Ge}-\mathrm{Cl}\) bond lengths in these compounds?
Why does xenon react with fluorine, whereas neon does not?
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