Chapter 7: Problem 80
Why does xenon react with fluorine, whereas neon does not?
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Chapter 7: Problem 80
Why does xenon react with fluorine, whereas neon does not?
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An element \(X\) reacts with \(\mathrm{F}_{2}(g)\) to form the molecular product shown below. (a) Write a balanced equation for this reaction (do not worry about the phases for \(X\) and the product). (b) Do you think that \(X\) is a metal or nonmetal? Explain. [Section 7.6]
(a) Why are ionization energies always positive quantities? (b) Why does \(\mathrm{F}\) have a larger first ionization energy than \(\mathrm{O}\) ? (c) Why is the second ionization energy of an atom always greater than its first ionization energy?
Until the early 1960 s the group 8 A elements were called the inert gases; before that they were called the rare gases. The term rare gases was dropped after it was discovered that argon accounts for roughly \(1 \%\) of Earth's atmosphere. (a) Why was the term inert gases dropped? (b) What discovery triggered this change in name? (c) What name is applied to the group now?
One way to measure ionization energies is photoelectron spectroscopy (PES), a technique based on the photoelectric effect. em (Section 6.2) In PES, monochromatic light is directed onto a sample, causing electrons to be emitted. The kinetic energy of the emitted electrons is measured. The difference between the energy of the photons and the kinetic energy of the electrons corresponds to the energy needed to remove the electrons (that is, the ionization energy). Suppose that a PES experiment is performed in which mercury vapor is irradiated with ultraviolet light of wavelength \(58.4 \mathrm{~nm}\). (a) What is the energy of a photon of this light, in \(\mathrm{eV}\) ? (b) Write an equation that shows the process corresponding to the first ionization energy of \(\mathrm{Hg}\). (c) The kinetic energy of the emitted electrons is measured to be \(10.75 \mathrm{eV}\). What is the first ionization energy of \(\mathrm{Hg}\), in \(\mathrm{kJ} / \mathrm{mol} ?\) (d) With reference to Figure \(7.11\), determine which of the halogen elements has a first ionization energy closest to that of mercury.
For each of the following sets of atoms and ions, arrange the members in order of increasing size: (a) \(\mathrm{Se}^{2-}, \mathrm{Te}^{2-}, \mathrm{Se}\); (b) \(\mathrm{Co}^{3+}, \mathrm{Fe}^{2+}, \mathrm{Fe}^{3+}\), (c) \(\mathrm{Ca}, \mathrm{Ti}^{4+}, \mathrm{Sc}^{3+}\) (d) \(\mathrm{Be}^{2+}, \mathrm{Na}^{+}, \mathrm{Ne}\)
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