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Starch is a carbohydrate polymer composed of glucose units. It is found in plants as both amylose and amylopectin. Amylose is a linear polymer characterized by α(1→4) glycosidic linkages between the glucose monomers. In contrast, amylopectin is a branched polymer with α(1→4) glycosidic linkages in the linear chains and branching points formed by α(1→6) glycosidic linkages. Both amylose and amylopectin molecules form helical structures, allowing them to store energy efficiently.

Glycogen is the main carbohydrate storage molecule in animal cells. It is also composed of glucose units, but it is more extensively branched than amylopectin. The glucose monomers in glycogen are primarily linked by α(1→4) glycosidic linkages, with branching points occurring every 8-12 glucose units through α(1→6) linkages. Glycogen has a highly compact structure, making it suitable for rapid energy release.

Cellulose is the primary component of plant cell walls, providing structural support and rigidity to the cell. Unlike starch and glycogen, cellulose is composed of β-glucose units, resulting in a linear chain structure with β(1→4) glycosidic linkages between glucose units. Due to these linkages, cellulose chains form linear, unbranched structures with multiple parallel chains joined together by hydrogen bonding, forming a strong crystalline arrangement. As a result, cellulose is rigid and difficult to break down, making it ideal for plant cell walls. In summary, the structural differences among starch, glycogen, and cellulose lie in their molecular arrangements and bonding. Starch (both amylose and amylopectin) and glycogen have α-glucose units connected by α(1→4) glycosidic linkages, with amylopectin and glycogen having additional α(1→6) linkages at branching points. Cellulose, on the other hand, consists of β-glucose units connected by β(1→4) glycosidic linkages.