Chapter 23: Problem 7
Two of the most heavily utilized metals are aluminum and iron. What are the most important natural sources of these elements? In what oxidation state is each metal found in nature?
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Chapter 23: Problem 7
Two of the most heavily utilized metals are aluminum and iron. What are the most important natural sources of these elements? In what oxidation state is each metal found in nature?
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Explain why aluminum, magnesium, and sodium metals are obtained by electrolysis instead of by reduction with chemical reducing agents.
Use the thermodynamicquantities given in Appendix C to calculate \(\Delta G^{\circ}, \Delta H^{\circ}\), and \(\Delta S^{\circ}\) for the reaction corresponding to roasting of \(\mathrm{PbO}\) in a CO atmosphere (Equation 23.5). Approximate the thermodynamic quantities of \(\mathrm{Pb}(I)\) using the thermodynamic properties of \(\mathrm{Pb}(s)\). Is this reaction spontaneous at \(25^{\circ} \mathrm{C}\) under standard conditions? Is it exothermic or endothermic?
Complete and balance each equation: (a) \(\mathrm{PbS}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{~g}) \stackrel{\Delta}{\longrightarrow}\) (b) \(\mathrm{CoCO}_{3}(\mathrm{~s}) \stackrel{\Delta}{\longrightarrow}\) (c) \(\mathrm{WO}_{3}(\mathrm{~s})+\mathrm{H}_{2}(\mathrm{~g}) \stackrel{\Delta}{\longrightarrow}\) (d) \(\mathrm{VCl}_{3}(g)+\mathrm{K}(I) \longrightarrow\) (e) \(\mathrm{BaO}(s)+\mathrm{P}_{2} \mathrm{O}_{5}(l) \longrightarrow\)
The element vanadium exhibits multiple oxidation states in its compounds, including \(+2\). The compound \(\mathrm{VCl}_{2}\) is known, whereas \(\mathrm{ScCl}_{2}\) is unknown. Use electron configurations and effective nuclear charges to account for this difference in behavior.
Write the formula for the oxide corresponding to the highest expected oxidation state for (a) \(\mathrm{Cd}\), (b) \(\mathrm{V}\), (c) \(\mathrm{W}\), (d) Ru.
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