Chapter 23: Problem 58
Explain why aluminum, magnesium, and sodium metals are obtained by electrolysis instead of by reduction with chemical reducing agents.
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Chapter 23: Problem 58
Explain why aluminum, magnesium, and sodium metals are obtained by electrolysis instead of by reduction with chemical reducing agents.
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What role does each of the following materials play in the chemical processes that occur in a blast furnace: (a) air, (b) limestone, (c) coke (d) water? Write balanced chemical equations to illustrate your answers.
Indicate whether each of the following compounds is expected to be diamagnetic or paramagnetic, and give a reason for your answer in each case: (a) \(\mathrm{NbCl}_{5}\), (b) \(\mathrm{CrCl}_{2}\), (c) \(\mathrm{CuCl}\), (d) \(\mathrm{RuO}_{4}\), (e) \(\mathrm{NiCl}_{2}\).
Based on the chemistry described in this chapter and others, propose balanced chemical equations for the following sequence of reactions involving nickel: (a) The ore millerite, which contains NiS, is roasted in an atmosphere of oxygen to produce an oxide. (b) The oxide is reduced to the metal, using coke. (c) Dissolving the metal in hydrochloric acid produces a green solution. (d) Adding excess sodium hydroxide to the solution causes a gelatinous green material to precipitate. (e) Upon heating, the green material loses water and yields a green powder.
(a) On the atomic level, what distinguishes ferromagnetic, ferrimagnetic, and antiferromagnetic materials from each other? (b) Which one of these types of magnetic materials cannot be used to make a permanent magnet?
(a) Pyrolusite \(\left(\mathrm{MnO}_{2}\right)\) is a commercially important mineral of manganese. What is the oxidation state of \(\mathrm{Mn}\) in this metal? (b) Name some reagents that might be used to reduce this ore to the metal.
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