Chapter 18: Problem 55
What properties of CFCs make them ideal for various commercial applications but also make them a longterm problem in the stratosphere?
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Chapter 18: Problem 55
What properties of CFCs make them ideal for various commercial applications but also make them a longterm problem in the stratosphere?
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The Baeyer-Villiger reaction is a classic organic oxidation reaction for converting ketones to lactones, as in this reaction: The reaction is used in the manufacture of plastics and pharmaceuticals. The reactant 3 -chloroperbenzoic acid is somewhat shock sensitive, however, and prone to explode Also, 3 -chlorobenzoic acid is a waste product. An alternative process being developed uses hydrogen peroxide and a catalyst consisting of tin deposited within a solid support. The catalyst is readily recovered from the reaction mixture. (a) What would you expect to be the other product of oxidation of the ketone to lactone by hydrogen peroxide? (b) What principles of green chemistry are addressed by use of the proposed process?
You are working with an artist who has been commissioned to make a sculpture for a big city in the eastem United States. The artist is wondering what material to use to make her sculpture, because she has heard that acid rain in the eastern U.S. might destroy it over time. You take samples of granite, marble, bronze, and other materials, and place them outdoors for a long time in the big city. You periodically examine the appearance and measure the mass of the samples. (a) What observations would lead you to conclude that one, or more, of the materials were well-suited for the sculpture? (b) What chemical process (or processes) is (are) the most likely responsible for any observed changes in the materials? [Section \(18.4]\)
The average daily mass of \(\mathrm{O}_{2}\) taken up by sewage discharged in the United States is \(59 \mathrm{~g}\) per person. How many liters of water at 9 ppm \(\mathrm{O}_{2}\) are totally depleted of oxygen in 1 day by a population of 120,000 people?
Molecules in the upper atmosphere tend to contain double and triple bonds rather than single bonds. Suggest an explanation. [Section 18.2]
The estimated average concentration of \(\mathrm{NO}_{2}\) in air in the United States in 2006 was \(0.016\) ppm. (a) Calculate the partial pressure of the \(\mathrm{NO}_{2}\) in a sample of this air when the atmospheric pressure is 755 torr \((99.1 \mathrm{kPa}) .\) (b) How many molecules of \(\mathrm{NO}_{2}\) are present under these conditions at \(20^{\circ} \mathrm{C}\) in a room that measures \(15 \times 14 \times 8 \mathrm{ft}\) ?
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