Chapter 18: Problem 53
If an average \(\mathrm{O}_{3}\) molecule "lives" only \(100-200\) seconds in the stratosphere before undergoing dissociation, how can \(\mathrm{O}_{3}\) offer any protection from ultraviolet radiation?
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Chapter 18: Problem 53
If an average \(\mathrm{O}_{3}\) molecule "lives" only \(100-200\) seconds in the stratosphere before undergoing dissociation, how can \(\mathrm{O}_{3}\) offer any protection from ultraviolet radiation?
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Bioremediationis the process by which bacteria repair their environment in response, for example, to an oil spill The efficiency of bacteria for "eating" hydrocarbons depends on the amount of axygen in the system, \(\mathrm{pH}\), temperature, and many other factors In a certain oil spill, hydrocarbons from the oil disappeared with a first-order rate constant of \(2 \times 10^{-6} \mathrm{~s}^{-1}\). How many days did it take for the hydrocarbons to decrease to \(10 \%\) of their initial value?
Would you expect the substance \(\mathrm{CFBr}_{3}\) to be effective in depleting the ozone layer, assuming that it is present in the stratosphere? Explain.
The precipitation of \(\mathrm{A} \mathrm{L}(\mathrm{OH})_{3}\left(K_{\text {sp }}=1.3 \times 10^{-33}\right.\) ) is sometimes used to purify water. (a) Estimate the \(\mathrm{pH}\) at wh?ch precipitation of \(\mathrm{Al}(\mathrm{OH})_{3}\) will begin if \(5.0 \mathrm{lb}\) of \(\mathrm{Al}_{2}\left(\mathrm{SO}_{4}\right)_{3}\) is added to \(2000 \mathrm{gal}\) of water. (b) Approximately how many pounds of \(\mathrm{CaO}\) must be added to the water to achieve this \(\mathrm{pH}\) ?
In \(\mathrm{CF}_{3} \mathrm{Cl}\) the \(\mathrm{C}-\mathrm{Cl}\) bond- dissociation energy is \(339 \mathrm{~kJ} / \mathrm{mol}\). In \(\mathrm{CCl}_{4}\) the \(\mathrm{C}-\mathrm{Cl}\) bond-dissociation energy is \(293 \mathrm{~kJ} / \mathrm{mol}\). What is the range of wavelengths of photons that can cause \(\mathrm{C}-\mathrm{Cl}\) bond rupture in one molecule but not in the other?
(a) Write a chemical equation that describes the attack of acid rain on limestone, \(\mathrm{CaCO}_{3}\). (b) If a limestone sculpture were treated to form a surface layer of calcium sulfate, would this help to slow down the effects of acid rain? Explain.
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