Chapter 13: Problem 1
What does it mean to describe a reaction as "reversible"?
Short Answer
Step by step solution
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none}
Learning Materials
Features
Discover
Chapter 13: Problem 1
What does it mean to describe a reaction as "reversible"?
These are the key concepts you need to understand to accurately answer the question.
All the tools & learning materials you need for study success - in one app.
Get started for free
Show that the complete chemical equation, the total ionic equation, and the net ionic equation for the reaction represented by the equation \(\mathrm{KI}(a q)+\mathrm{I}_{2}(a q) \rightleftharpoons \mathrm{KI}_{3}(a q)\) give the same expression for the reaction quotient. \(\mathrm{KI}_{3}\) is composed of the ions \(K^{+}\) and \(I_{3}^{-}\)
Pure iron metal can be produced by the reduction of iron(III) oxide with hydrogen gas. (a) Write the expression for the equilibrium constant \(\left(K_{c}\right)\) for the reversible reaction \(\mathrm{Fe}_{2} \mathrm{O}_{3}(s)+3 \mathrm{H}_{2}(g) \rightleftharpoons 2 \mathrm{Fe}(s)+3 \mathrm{H}_{2} \mathrm{O}(g) \quad \Delta H=98.7 \mathrm{kJ}\) (b) What will happen to the concentration of each reactant and product at equilibrium if more Fe is added? (c) What will happen to the concentration of each reactant and product at equilibrium if \(\mathrm{H}_{2} \mathrm{O}\) is removed? (d) What will happen to the concentration of each reactant and product at equilibrium if \(\mathrm{H}_{2}\) is added? (e) What will happen to the concentration of each reactant and product at equilibrium if the volume of the reaction vessel is decreased? (f) What will happen to the concentration of each reactant and product at equilibrium if the temperature of the system is increased?
Assume that the change in concentration of \(\mathrm{COCl}_{2}\) is small enough to be neglected in the following problem. (a) Calculate the equilibrium concentration of all species in an equilibrium mixture that results from the decomposition of \(\mathrm{COCl}_{2}\) with an initial concentration of \(0.3166 \mathrm{M}\). \(\operatorname{COCl}_{2}(g) \rightleftharpoons \operatorname{CO}(g)+\mathrm{Cl}_{2}(g) \quad K_{c}=2.2 \times 10^{-10}\) (b) Confirm that the change is small enough to be neglected.
Consider the following reaction at 298 K: \(\mathrm{N}_{2} \mathrm{O}_{4}(g) \rightleftharpoons 2 \mathrm{NO}_{2}(g)\) \(K_{P}=0.142\) What is the standard free energy change at this temperature? Describe what happens to the initial system, where the reactants and products are in standard states, as it approaches equilibrium.
If a reaction is reversible, when can it be said to have reached equilibrium?
What do you think about this solution?
We value your feedback to improve our textbook solutions.