Chapter 13: Problem 3
If a reaction is reversible, when can it be said to have reached equilibrium?
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Chapter 13: Problem 3
If a reaction is reversible, when can it be said to have reached equilibrium?
These are the key concepts you need to understand to accurately answer the question.
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Write the mathematical expression for the reaction quotient, \(Q_{c}\), for each of the following reactions: (a) \(\mathrm{N}_{2}(g)+3 \mathrm{H}_{2}(g) \rightleftharpoons 2 \mathrm{NH}_{3}(g)\) (b) \(4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) \rightleftharpoons 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g)\) (c) \(\mathrm{N}_{2} \mathrm{O}_{4}(g)=2 \mathrm{NO}_{2}(g)\) (d) \(\mathrm{CO}_{2}(g)+\mathrm{H}_{2}(g) \rightleftharpoons \mathrm{CO}(g)+\mathrm{H}_{2} \mathrm{O}(g)\) (e) \(\mathrm{NH}_{4} \mathrm{Cl}(s)=\mathrm{NH}_{3}(g)+\mathrm{HCl}(g)\) (f) \(2 \mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}(s) \rightleftharpoons 2 \mathrm{PbO}(s)+4 \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g)\) (g) \(2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g)=2 \mathrm{H}_{2} \mathrm{O}(l)\) (h) \(S_{8}(g) \rightleftharpoons 8 S(g)\)
A solution is saturated with silver sulfate and contains excess solid silver sulfate: \(\mathrm{Ag}_{2} \mathrm{SO}_{4}(s) \rightleftharpoons 2 \mathrm{Ag}^{+}(a q)+\mathrm{SO}_{4}^{2-}(a q)\) A small amount of solid silver sulfate containing a radioactive isotope of silver is added to this solution. Within a few minutes, a portion of the solution phase is sampled and tests positive for radioactive \(\mathrm{Ag}^{+}\) ions. Explain this observation.
When heated, iodine vapor dissociates according to this equation: \(\mathbf{I}_{2}(g) \rightleftharpoons 2 \mathbf{I}(g)\) At \(1274 \mathrm{K},\) a sample exhibits a partial pressure of \(\mathrm{I}_{2}\) of 0.1122 atm and a partial pressure due to 1 atoms of 0.1378 atm. Determine the value of the equilibrium constant, \(K_{P}\), for the decomposition at \(1274 \mathrm{K}\).
Methanol can be prepared from carbon monoxide and hydrogen at high temperature and pressure in the presence of a suitable catalyst. (a) Write the expression for the equilibrium constant \(\left(K_{c}\right)\) for the reversible reaction \(2 \mathrm{H}_{2}(g)+\mathrm{CO}(g) \rightleftharpoons \mathrm{CH}_{3} \mathrm{OH}(g) \quad \Delta H=-90.2 \mathrm{kJ}\) (b) What will happen to the concentrations of \(\mathrm{H}_{2}, \mathrm{CO},\) and \(\mathrm{CH}_{3} \mathrm{OH}\) at equilibrium if more \(\mathrm{H}_{2}\) is added? (c) What will happen to the concentrations of \(\mathrm{H}_{2}, \mathrm{CO},\) and \(\mathrm{CH}_{3} \mathrm{OH}\) at equilibrium if CO is removed? (d) What will happen to the concentrations of \(\mathrm{H}_{2}, \mathrm{CO},\) and \(\mathrm{CH}_{3} \mathrm{OH}\) at equilibrium if \(\mathrm{CH}_{3} \mathrm{OH}\) is added? (e) What will happen to the concentrations of \(\mathrm{H}_{2}, \mathrm{CO},\) and \(\mathrm{CH}_{3} \mathrm{OH}\) at equilibrium if the temperature of the system is increased?
The following reaction occurs when a burner on a gas stove is lit: \(\mathrm{CH}_{4}(g)+2 \mathrm{O}_{2}(g) \rightleftharpoons \mathrm{CO}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(g)\)
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