Chapter 13: Problem 3
If a reaction is reversible, when can it be said to have reached equilibrium?
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Chapter 13: Problem 3
If a reaction is reversible, when can it be said to have reached equilibrium?
These are the key concepts you need to understand to accurately answer the question.
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Consider the equilibrium \(4 \mathrm{NO}_{2}(g)+6 \mathrm{H}_{2} \mathrm{O}(g) \rightleftharpoons 4 \mathrm{NH}_{3}(g)+7 \mathrm{O}_{2}(g)\) (a) What is the expression for the equilibrium constant \(\left(K_{c}\right)\) of the reaction? (b) How must the concentration of \(\mathrm{NH}_{3}\) change to reach equilibrium if the reaction quotient is less than the equilibrium constant? (c) If the reaction were at equilibrium, how would an increase in the volume of the reaction vessel affect the pressure of \(\mathrm{NO}_{2} ?\) (d) If the change in the pressure of \(\mathrm{NO}_{2}\) is 28 torr as a mixture of the four gases reaches equilibrium, how much will the pressure of \(\mathrm{O}_{2}\) change?
Methanol can be prepared from carbon monoxide and hydrogen at high temperature and pressure in the presence of a suitable catalyst. (a) Write the expression for the equilibrium constant \(\left(K_{c}\right)\) for the reversible reaction \(2 \mathrm{H}_{2}(g)+\mathrm{CO}(g) \rightleftharpoons \mathrm{CH}_{3} \mathrm{OH}(g) \quad \Delta H=-90.2 \mathrm{kJ}\) (b) What will happen to the concentrations of \(\mathrm{H}_{2}, \mathrm{CO},\) and \(\mathrm{CH}_{3} \mathrm{OH}\) at equilibrium if more \(\mathrm{H}_{2}\) is added? (c) What will happen to the concentrations of \(\mathrm{H}_{2}, \mathrm{CO},\) and \(\mathrm{CH}_{3} \mathrm{OH}\) at equilibrium if CO is removed? (d) What will happen to the concentrations of \(\mathrm{H}_{2}, \mathrm{CO},\) and \(\mathrm{CH}_{3} \mathrm{OH}\) at equilibrium if \(\mathrm{CH}_{3} \mathrm{OH}\) is added? (e) What will happen to the concentrations of \(\mathrm{H}_{2}, \mathrm{CO},\) and \(\mathrm{CH}_{3} \mathrm{OH}\) at equilibrium if the temperature of the system is increased?
A reaction is represented by this equation: \(2 \mathrm{W}(a q) \rightleftharpoons \mathrm{X}(a q)+2 \mathrm{Y}(a q) \quad K_{c}=5 \times 10^{-4}\) (a) Write the mathematical expression for the equilibrium constant. (b) Using concentrations of \(\leq 1 M,\) identify two sets of concentrations that describe a mixture of \(\mathrm{W}, \mathrm{X},\) and \(\mathrm{Y}\) at equilibrium.
Acetic acid is a weak acid that reacts with water according to this equation: \(\mathrm{CH}_{3} \mathrm{CO}_{2} \mathrm{H}(a q)+\mathrm{H}_{2} \mathrm{O}(a q) \rightleftharpoons \mathrm{H}_{3} \mathrm{O}^{+}(a q)+\mathrm{CH}_{3} \mathrm{CO}_{2}^{-}(a q)\) Will any of the following increase the percent of acetic acid that reacts and produces \(\mathrm{CH}_{3} \mathrm{CO}_{2}^{-}\) ion? (a) Addition of HCl (b) Addition of NaOH (c) Addition of \(\mathrm{NaCH}_{3} \mathrm{CO}_{2}\)
Write the mathematical expression for the reaction quotient, \(Q_{c}\) for each of the following reactions: (a) \(\mathrm{CH}_{4}(\mathrm{g})+\mathrm{C}_{2}(\mathrm{g})=\mathrm{CH}_{3} \mathrm{Cl}(\mathrm{g})+\mathrm{HCl}(g)\) (b) \(\mathrm{N}_{2}(g)+\mathrm{O}_{2}(g)=2 \mathrm{NO}(g)\) (c) \(2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g)\) (d) \(\operatorname{BaSO}_{3}(s)=\operatorname{BaO}(s)+\operatorname{SO}_{2}(g)\) (e) \(\mathrm{P}_{4}(g)+5 \mathrm{O}_{2}(g) \rightleftharpoons \mathrm{P}_{4} \mathrm{O}_{10}(s)\) (f) \(\operatorname{Br}_{2}(g)=2 \operatorname{Br}(g)\) (g) \(\mathrm{CH}_{4}(g)+2 \mathrm{O}_{2}(g) \rightleftharpoons \mathrm{CO}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(I)\) (h) \(\operatorname{CuSO}_{4} \cdot 5 \mathrm{H}_{2} \mathrm{O}(s)=\mathrm{CuSO}_{4}(s)+5 \mathrm{H}_{2} \mathrm{O}(g)\)
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