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What mass of oxalic acid, \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4},\) is required to prepare \(250 .\) mL of a solution that has a concentration of \(0.15 \mathrm{M}\) \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{D}_{4} ?\)

Short Answer

Expert verified
The required mass of oxalic acid is approximately 3.38 g.

Step by step solution

01

Understand the problem

We are asked to find the mass of oxalic acid needed to make 250 mL of a 0.15 M solution. The formula for molarity (M) is given by \( M = \frac{n}{V} \), where \( n \) is the number of moles, and \( V \) is the volume in liters.
02

Convert Volume to Liters

The given volume is 250 mL. Convert this to liters by dividing by 1000. So, \( 250 \text{ mL} = 0.250 \text{ L} \).
03

Calculate Moles of Oxalic Acid

Use the molarity formula to find the moles of oxalic acid needed. Rearrange the formula as \( n = M \times V \). Substitute the values: \( n = 0.15 \text{ M} \times 0.250 \text{ L} = 0.0375 \text{ moles} \).
04

Determine Molar Mass of Oxalic Acid

The molar mass of oxalic acid, \( \mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4} \), can be calculated by adding the atomic masses: \( 2 \times 1.01 \text{ (H)} + 2 \times 12.01 \text{ (C)} + 4 \times 16.00 \text{ (O)} = 90.03 \text{ g/mol} \).
05

Calculate Mass of Oxalic Acid

Use the formula \( \text{mass} = n \times \text{molar mass} \). Substitute the values: \( \text{mass} = 0.0375 \text{ moles} \times 90.03 \text{ g/mol} = 3.376125 \text{ g} \), which can be rounded to approximately 3.38 g.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molarity
Molarity is an essential concept in chemistry that helps us understand the concentration of a solution. It is defined as the number of moles of solute present per liter of solution. The formula to calculate molarity is given by:\[ M = \frac{n}{V} \]where \( M \) represents molarity, \( n \) is the number of moles of solute, and \( V \) is the volume of the solution in liters.

Molarity provides a way to quantify the concentration of a substance in a given volume, making it crucial for solution preparation. For example, in our exercise, a solution of oxalic acid with a molarity of 0.15 M means there are 0.15 moles of oxalic acid in every liter of that solution. This standardization allows chemists to precisely control reactions and predict outcomes.
Conversion of Units
Conversion of units is a vital skill in chemistry since measurements often need to be expressed in different units. In the exercise, the given volume of oxalic acid solution is 250 mL. To use this in molarity calculations, we need to convert it to liters.

The conversion between milliliters and liters is straightforward as there are 1000 milliliters in a liter. Thus, by dividing the volume in milliliters by 1000, we convert 250 mL to 0.250 L:\[ 250 \text{ mL} \times \frac{1 \text{ L}}{1000 \text{ mL}} = 0.250 \text{ L} \]This step is crucial for using consistent units across calculations, ensuring accuracy in the solution preparation process.
Molar Mass Calculation
Molar mass is the mass of one mole of a given compound and is expressed in grams per mole (g/mol). Calculating the molar mass involves adding the atomic masses of all the atoms in the molecule.

For oxalic acid, \( \text{H}_{2} \text{C}_{2} \text{O}_{4} \), the calculation involves:
  • Hydrogen (H): 2 atoms \( \times 1.01\, \text{g/mol} = 2.02\, \text{g/mol} \)
  • Carbon (C): 2 atoms \( \times 12.01\, \text{g/mol} = 24.02\, \text{g/mol} \)
  • Oxygen (O): 4 atoms \( \times 16.00\, \text{g/mol} = 64.00\, \text{g/mol} \)
Summing these gives the molar mass of oxalic acid as 90.03 g/mol:\[ \text{Molar mass of } \text{H}_{2} \text{C}_{2} \text{O}_{4} = 2.02 + 24.02 + 64.00 = 90.03\, \text{g/mol} \]This value is key for determining the mass of the compound required when preparing a solution.
Stoichiometry
Stoichiometry is a branch of chemistry that deals with the quantitative relationships between reactants and products in a chemical reaction. It is crucial to our example as it helps us calculate the amount of reactant needed to achieve a desired concentration.

In the context of solution preparation, stoichiometry allows us to convert moles of a substance (derived from its molarity and volume) to its mass by using the molar mass. For the exercise, the number of moles \( n \) of oxalic acid required is calculated:\[ n = M \times V = 0.15 \text{ M} \times 0.250 \text{ L} = 0.0375 \text{ moles} \]By knowing the number of moles, we use stoichiometry to find the mass:\[ \text{mass} = n \times \text{molar mass} = 0.0375 \text{ moles} \times 90.03 \text{ g/mol} \approx 3.38 \text{ g} \]Understanding stoichiometry ensures precise measurement and preparation in chemistry, bridging theoretical calculations with practical applications.

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