Chapter 18: Problem 98
Which of the following barium salts should dissolve in a strong acid such as HCl: \(\mathrm{Ba}(\mathrm{OH})_{2}, \mathrm{BaSO}_{4},\) or \(\mathrm{BaCO}_{3} ?\)
Short Answer
Expert verified
Ba(OH)2 and BaCO3 will dissolve in HCl.
Step by step solution
01
Understanding the solubility of Ba(OH)2 in HCl
Barium hydroxide, \( \mathrm{Ba(OH)_2} \), is a strong base. When \( \mathrm{Ba(OH)_2} \) is added to a strong acid like \( \mathrm{HCl} \), it will react to form water and a soluble salt (\( \mathrm{BaCl_2} \)). This is a classic example of an acid-base reaction where a base dissolves in an acid.
02
Considering the solubility of BaSO4 in HCl
Barium sulfate, \( \mathrm{BaSO_4} \), is known for being highly insoluble in water and does not typically react with strong acids like \( \mathrm{HCl} \). The sulfate ion is quite stable and does not form a more soluble compound upon reacting with hydrochloric acid.
03
Analyzing the solubility of BaCO3 in HCl
Barium carbonate, \( \mathrm{BaCO_3} \), reacts with strong acids like \( \mathrm{HCl} \) to produce water and carbon dioxide along with a soluble salt (\( \mathrm{BaCl_2} \)). The reaction can be represented as: \[ \mathrm{BaCO_3 (s) + 2 HCl (aq) \rightarrow BaCl_2 (aq) + H_2O (l) + CO_2 (g)} \]. This indicates that \( \mathrm{BaCO_3} \) will dissolve in \( \mathrm{HCl} \).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Barium Hydroxide and HCl Reaction
Barium hydroxide, denoted as \( \mathrm{Ba(OH)_2} \), participates in an acid-base reaction when introduced to hydrochloric acid (\( \mathrm{HCl} \)). This reaction is a classic example of how a strong base interacts with a strong acid.
The equation for the reaction is as follows:
Understanding this concept clarifies why \( \mathrm{Ba(OH)_2} \) can easily dissolve in strong acids, making it a great candidate for neutralizing acidic solutions.
The equation for the reaction is as follows:
- \( \mathrm{Ba(OH)_2(s) + 2HCl(aq) \rightarrow BaCl_2(aq) + 2H_2O(l)} \)
Understanding this concept clarifies why \( \mathrm{Ba(OH)_2} \) can easily dissolve in strong acids, making it a great candidate for neutralizing acidic solutions.
Barium Sulfate Insolubility
Barium sulfate, chemically expressed as \( \mathrm{BaSO_4} \), is characteristically known for its insolubility. It does not dissolve easily in water or even in strong acids such as hydrochloric acid (\( \mathrm{HCl} \)). This widespread property can be attributed to the stable nature of the sulfate ion (\( \mathrm{SO_4^{2-}} \)).
- Unlike some other salts, \( \mathrm{BaSO_4} \) doesn't react with \( \mathrm{HCl} \) to form more soluble compounds.
- The strong ionic bonds in \( \mathrm{BaSO_4} \) contribute to its persistent insolubility.
Barium Carbonate and HCl Reaction
Barium carbonate (\( \mathrm{BaCO_3} \)) behaves differently when mixed with strong acids like \( \mathrm{HCl} \). This compound readily reacts with hydrochloric acid in a notable manner that results in the evolution of carbon dioxide gas.
- The reaction is: \[ \mathrm{BaCO_3(s) + 2HCl(aq) \rightarrow BaCl_2(aq) + H_2O(l) + CO_2(g)} \]
- Here, \( \mathrm{BaCO_3} \) dissolves as it turns into soluble barium chloride while releasing \( \mathrm{CO_2} \) as a byproduct.