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Write a chemical equation describing the reaction between glycerol and stearic acid to give glyceryl tristearate.

Short Answer

Expert verified
C3H8O3 + 3 C18H36O2 → C57H110O6 + 3 H2O

Step by step solution

01

Identify the Reactants

The reactants in the given reaction are glycerol (C3H8O3) and stearic acid (C18H36O2). We need to use the structural formulas of these compounds to proceed with the reaction.
02

Understand the Reaction Type

The reaction is an esterification, where an alcohol (glycerol) reacts with carboxylic acids (stearic acid) to form an ester (glyceryl tristearate) and water.
03

Determine the Reaction Stoichiometry

The reaction involves three molecules of stearic acid reacting with one molecule of glycerol. This is essential for balancing the reaction equation properly.
04

Write the Structural Formula of Reactants

Glycerol's structural formula is HOCH2-CHOH-CH2OH and stearic acid's structural formula is CH3(CH2)16COOH. Write these to visualize the molecules involved.
05

Connect Reactants to Form Glyceryl Tristearate

During the esterification reaction, three hydroxyl groups in glycerol will react with the carboxyl groups of three stearic acid molecules, releasing three water molecules. This forms the ester linkage between them.
06

Write the Chemical Equation

The balanced chemical equation is: C3H8O3 + 3 C18H36O2 → C57H110O6 + 3 H2O. This shows glycerol and stearic acid forming glyceryl tristearate and water.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Glycerol
Glycerol is a simple yet significant molecule. As a clear, odorless liquid with a sweet taste, it is commonly used in various industries, ranging from food to cosmetics. In chemistry, glycerol is an alcohol composed of three hydroxyl (\(-OH\)) groups. Its chemical formula is \(C_3H_8O_3\), and its structural formula is HOCH_2-CHOH-CH_2OH. These hydroxyl groups are critical because they enable glycerol to engage in esterification reactions, like the one forming glyceryl tristearate.
A key property of glycerol is its ability to form hydrogen bonds, making it extremely soluble in water. This also allows it to act as a binding agent in various substances. When participating in reactions like esterification, glycerol's hydroxyl groups react with acids to form esters and release water molecules. This reaction plays a vital role in creating a wide array of products, including certain fats and oils.
Exploring Stearic Acid
Stearic acid is a saturated fatty acid, typically found in animal and plant fats. Its chemical structure is represented by CH_3(CH_2)_{16}COOH, highlighting its long carbon chain of 18 carbon atoms. This long chain contributes to its solid form at room temperature, unlike unsaturated fatty acids with one or more double bonds.
Stearic acid is an essential component in the formation of esters due to its carboxylic acid (\(-COOH\)) group. In esterification reactions, it reacts with alcohols such as glycerol to form esters. This process involves the carboxyl group reacting with hydroxyl groups, resulting in the release of water molecules. The reaction with glycerol to form glyceryl tristearate is a prime example of its role in biochemistry and industrial processes.
  • Common uses include candle-making, cosmetics, and as a hardening agent in soaps.
  • It's non-toxic and biodegradable, making products safer and eco-friendly.
Formation of Glyceryl Tristearate
Glyceryl tristearate, also known as tristearin, is an ester formed through the esterification of glycerol and stearic acid. The chemical equation for this reaction is: \[C_3H_8O_3 + 3 \, C_{18}H_{36}O_2 \rightarrow C_{57}H_{110}O_6 + 3 \, H_2O\].
In this reaction, one glycerol molecule bonds with three stearic acid molecules. The hydroxyl groups from glycerol react with the carboxyl groups of stearic acid, releasing water and forming ester linkages. This results in the production of glyceryl tristearate and water.
Glyceryl tristearate is a primary component of certain fats found naturally in animal and plant matter. In industry, it is often used in food processing, cosmetics, and pharmaceuticals due to its texture-enhancing properties. It solidifies easily, making it useful in products like margarine and lotions. By understanding this reaction, students can grasp the basics of esterification and its implications in both biological and practical realms.

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Most popular questions from this chapter

Maleic acid is prepared by the catalytic oxidation of benzene. It is a dicarboxylic acid; that is, it has two carboxylic acid groups. (a) Combustion of 0.125 g of the acid gives \(0.190 \mathrm{g}\) of \(\mathrm{CO}_{2}\) and \(0.0388 \mathrm{g}\) of \(\mathrm{H}_{2} \mathrm{O} .\) What is the empirical formula of the acid? (b) A 0.261 -g sample of the acid requires 34.60 mL of \(0.130 \mathrm{M} \mathrm{NaOH}\) for complete titration (so that the \(\mathrm{H}^{+}\) ions from both carboxylic acid groups are used). What is the molecular formula of the acid? (c) Draw a Lewis structure for the acid. (d) Describe the hybridization used by the C atoms. (e) What are the bond angles around each C atom?

Benzoic acid occurs in many berries. When humans eat berries, benzoic acid is converted to hippuric acid in the body by reaction with the amino acid glycine, \(\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2} \mathrm{H} .\) Draw the structure of hippuric acid, recognizing that it is an amide formed by reaction of the carboxylic acid group of benzoic acid and the amino group of glycine. Why is hippuric acid referred to as an acid?

A well-known company selling outdoor clothing has recently introduced jackets made of recycled polyethylene terephthalate (PET), the principal material in many softdrink bottles. Another company makes PET fibers by treating recycled bottles with methanol to give the diester dimethylterephthalate and ethylene glycol and then repolymerizing these compounds to give new PET. Write a chemical equation to show how the reaction of PET with methanol can give dimethylterephthalate and ethylene glycol.

Name the following amines (a) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\) (b) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{N}\) (c) \(\left(\mathrm{CH}_{3}\right)\left(\mathrm{C}_{2} \mathrm{H}_{5}\right) \mathrm{NH}\) (d) \(\mathrm{C}_{6} \mathrm{H}_{13} \mathrm{NH}_{2}\)

Draw structures for alkenes that have the formula \(\mathrm{C}_{3} \mathrm{H}_{5} \mathrm{Cl}\) and name each compound. (In these derivatives of propene, a chlorine atom replaces one hydrogen atom.)

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