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In an experiment, 1.056 g of a metal carbonate, containing an unknown metal \(\mathrm{M},\) is heated to give the metal oxide and \(0.376 \mathrm{g} \mathrm{CO}_{2}\). $$\mathrm{MCO}_{3}(\mathrm{s})+\text { heat } \rightarrow \mathrm{MO}(\mathrm{s})+\mathrm{CO}_{2}(\mathrm{g})$$ What is the identity of the metal \(\mathrm{M}\) ? (a) \(\mathrm{M}=\mathrm{Ni}\) (b) \(\mathrm{M}=\mathrm{Cu}\) (c) \(\mathrm{M}=\mathrm{Zn}\) (d) \(\mathrm{M}=\mathrm{Ba}\)

Short Answer

Expert verified
The metal is Zn (option c).

Step by step solution

01

Understand the Reaction

The given reaction is a thermal decomposition reaction: \( \text{MCO}_3 (s) \rightarrow \text{MO} (s) + \text{CO}_2 (g) \). We know the mass of the initial compound and the mass of \( \text{CO}_2 \) produced.
02

Calculate Moles of CO2

To determine the moles of \( \text{CO}_2 \), use the molar mass of \( \text{CO}_2 \), which is \( 44.01 \text{ g/mol} \). Calculate moles using the formula: \( \text{moles of } \text{CO}_2 = \frac{0.376 \text{ g}}{44.01 \text{ g/mol}} \approx 0.00854 \text{ mol} \).
03

Use Stoichiometry

From the balanced chemical equation \( \text{MCO}_3 \rightarrow \text{MO} + \text{CO}_2 \), we know the moles of \( \text{CO}_2 \) produced is equal to the moles of \( \text{MCO}_3 \) that decomposed. Thus, the moles of \( \text{MCO}_3 \) is \( 0.00854 \text{ mol} \).
04

Calculate Molar Mass of MCO3

The molar mass of \( \text{MCO}_3 \) is calculated using the formula: \( \text{molar mass of } \text{MCO}_3 = \frac{1.056 \text{ g}}{0.00854 \text{ mol}} \approx 123.69 \text{ g/mol} \).
05

Determine the Molar Mass of Metal M

The molar mass of \( \text{MCO}_3 \) is the sum of \( 44.01 \text{ g/mol} \) (\( \text{CO}_2 \)) and the molar mass of \( \text{MO} \). Therefore, the molar mass of \( \text{MO} \) is \( 123.69 - 44.01 = 79.68 \text{ g/mol} \). Since the molar mass of the unknown metal M corresponds approximately to Zn (65.38 g/mol), we check this value.
06

Identify the Metal M

The molar masses given in the options relate to different metals: Ni (58.69 g/mol), Cu (63.55 g/mol), Zn (65.38 g/mol), and Ba (137.33 g/mol). Comparing \( \text{Zn} \)'s molar mass, it is closest to the calculated value, confirming that the metal is Zn.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Thermal Decomposition
Thermal decomposition involves the breakdown of a chemical compound due to the application of heat. When a metal carbonate such as \( \text{MCO}_3 \) is heated, it decomposes into a metal oxide \( \text{MO} \) and carbon dioxide gas \( \text{CO}_2 \). This process is indicated by the equation: \( \text{MCO}_3 (s) \rightarrow \text{MO} (s) + \text{CO}_2 (g) \). Here, solid \( \text{MCO}_3 \) is transformed into the solid \( \text{MO} \) and gaseous \( \text{CO}_2 \), emphasizing the distinct phases of each component. Thermal decomposition reactions are common among metal carbonates. Metal carbonates like calcium carbonate, magnesium carbonate, and others usually decompose similarly when heated. The heat provides the necessary energy to break the chemical bonds in the metal carbonate, leading to the production of simpler compounds. Understanding this type of reaction is pivotal as it helps explain why certain compounds decompose under specific conditions and what kinds of products can be expected.
  • Important in industrial processes like the manufacture of lime.
  • Help us understand the stability of a compound at elevated temperatures.
Stoichiometry
In the context of chemical reactions, stoichiometry involves the calculation of relative quantities of reactants and products. The key principle is that the amount of products and reactants is directly proportional based on the balanced chemical equation. For the decomposition of metal carbonate \( \text{MCO}_3 \), the stoichiometry tells us that one mole of \( \text{MCO}_3 \) yields one mole of \( \text{MO} \) and one mole of \( \text{CO}_2 \). This is derived from the balanced reaction: \( \text{MCO}_3 \rightarrow \text{MO} + \text{CO}_2 \). This equal relationship implies that if you know the amount of one substance, you automatically know the amounts of the others if they react completely. By utilizing stoichiometry, it is possible to determine the unknown quantities like the identity of a metal in a compound by comparing moles between the products and reactants. Stoichiometry plays a crucial role in predicting the outcomes of reactions and establishing the efficiency of converting reactants to products.
  • Based on the law of conservation of mass.
  • Helps in calculating yields of chemical reactions.
Molar Mass Calculation
Calculating the molar mass of compounds is a foundational skill in chemistry, allowing us to turn measurements of mass into moles—a manageable and useable unit in stoichiometry. The molar mass of a compound is the sum of all the atomic masses of its constituent atoms. In the given exercise, the molar mass of \( \text{MCO}_3 \) was estimated by dividing the sample's mass by the moles. This calculation was executed as follows: - The formula for finding the molar mass is: \[ \text{Molar mass of } \text{MCO}_3 = \frac{\text{mass of the compound}}{\text{moles of the compound}} \] Given the mass of the compound and the moles of \( \text{CO}_2 \) (a stoichiometrically equivalent product), we can find the molar mass to match the potential metal candidates. Through calculating the molar mass, we can also ascertain the identity of unknown substances, like the mysterious metal \( \text{M} \) in the problem. This method highlights how practical and essential molar mass calculations are in chemical inquiries.
  • Important for converting between molar and mass quantities.
  • Assists in confirming compound identities.

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Most popular questions from this chapter

A \(4.000-\mathrm{g}\) sample containing \(\mathrm{KCl}\) and \(\mathrm{KClO}_{4}\) was dissolved in sufficient water to give \(250.00 \mathrm{mL}\) of solution. A 50.00 -mL portion of the solution required \(41.00 \mathrm{mL}\) of \(0.0750 \mathrm{M} \mathrm{AgNO}_{3}\) in a Mohr titration (page 209 ). Next, a 25.00 -mL portion of the original solution was treated with \(\mathrm{V}_{2}\left(\mathrm{SO}_{4}\right)_{3}\) to reduce the perchlorate ion to chloride, $$\begin{aligned} 8 \mathrm{V}^{3+}(\mathrm{aq})+\mathrm{ClO}_{4}^{-}(\mathrm{aq})+12 \mathrm{H}_{2} \mathrm{O}(\ell) \rightarrow & \\ \mathrm{Cl}^{-}(\mathrm{aq})+8 \mathrm{VO}^{2+}(\mathrm{aq}) &+8 \mathrm{H}_{3} \mathrm{O}^{+}(\mathrm{aq}) \end{aligned}$$ and the resulting solution was titrated with \(\mathrm{AgNO}_{3} .\) This titration required \(38.12 \mathrm{mL}\) of \(0.0750 \mathrm{M} \mathrm{AgNO}_{3} .\) What is the mass percent of KCl and \(\mathrm{KClO}_{4}\) in the mixture?

A solution of a dye was analyzed by spectrophotometry, and the following calibration data were collected. $$\begin{array}{|c|c|}\hline \text { Dye Concentration } & \begin{array}{c}\text { Absorbance }(A) \\\\\text { at } 475\mathrm{nm} \end{array} \\\\\hline 0.50 \times 10^{-6} \mathrm{M} & 0.24 \\\1.5 \times 10^{-6} \mathrm{M} & 0.36 \\\2.5 \times 10^{-6} \mathrm{M} & 0.44 \\\\\hline 3.5 \times 10^{-6} \mathrm{M} & 0.59 \\\4.5 \times 10^{-6} \mathrm{M} & 0.70\end{array}$$ (a) Construct a calibration plot, and determine the slope and intercept. (b) What is the dye concentration in a solution with \(A=0.52 ?\)

A solution of hydrochloric acid has a volume of \(125 \mathrm{mL}\) and a pH of \(2.56 .\) What mass of \(\mathrm{NaHCO}_{3}\) must be added to completely consume the HCl?

Cloth can be waterproofed by coating it with a silicone layer. This is done by exposing the cloth to \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{SiCl}_{2}\) vapor. The silicon compound reacts with OH groups on the cloth to form a waterproofing film (density \(=1.0 \mathrm{g} / \mathrm{cm}^{3}\) ) of \(\left[\left(\mathrm{CH}_{3}\right)_{2} \mathrm{SiO}\right]_{n},\) where \(n\) is a large integer number. $$\begin{aligned}&n\left(\mathrm{CH}_{3}\right)_{2} \mathrm{SiCl}_{2}+2 n \mathrm{OH}^{-} \rightarrow\\\&&2 n \mathrm{Cl}^{-}+n \mathrm{H}_{2} \mathrm{O}+\left[\left(\mathrm{CH}_{3}\right)_{2} \mathrm{SiO}\right]_{n} \end{aligned}$$ The coating is added layer by layer, with each layer of \(\left[\left(\mathrm{CH}_{3}\right)_{2} \mathrm{SiO}\right]_{n}\) being 0.60 nm thick. Suppose you want to waterproof a piece of cloth that is 3.00 square meters, and you want 250 layers of waterproofing compound on the cloth. What mass of \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{SiCl}_{2}\) do you need?

The metabolic disorder diabetes causes a buildup of acetone, \(\mathrm{CH}_{3} \mathrm{COCH}_{3,}\) in the blood. Acetone, a volatile compound, is exhaled, giving the breath of untreated diabetics a distinctive odor. The acetone is produced by a breakdown of fats in a series of reactions. The equation for the last step, the breakdown of acetoacetic acid to give acetone and \(\mathrm{CO}_{2},\) is $$\mathrm{CH}_{3} \mathrm{COCH}_{2} \mathrm{CO}_{2} \mathrm{H} \rightarrow \mathrm{CH}_{3} \mathrm{COCH}_{3}+\mathrm{CO}_{2}$$ What mass of acetone can be produced from \(125 \mathrm{mg}\) of acetoacetic acid?

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