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Phosphoric acid can supply one, two, or three \(\mathrm{H}_{3} \mathrm{O}^{+}\) ions in aqueous solution. Write balanced equations (like those for sulfuric acid on page 142 ) to show this successive loss of hydrogen ions.

Short Answer

Expert verified
Phosphoric acid dissociates in three steps to form \( \text{H}_2\text{PO}_4^- \), \( \text{HPO}_4^{2-} \), and \( \text{PO}_4^{3-} \) ions, respectively.

Step by step solution

01

Write the Formula of Phosphoric Acid

Phosphoric acid is represented by the chemical formula \( \text{H}_3\text{PO}_4 \). This compound can release hydrogen ions \( \text{H}^+ \) in a stepwise manner.
02

First Ionization

In the first ionization step, phosphoric acid loses one hydrogen ion to form dihydrogen phosphate ion:\[ \text{H}_3\text{PO}_4 (aq) \rightarrow \text{H}_2\text{PO}_4^- (aq) + \text{H}^+ (aq) \]
03

Second Ionization

The dihydrogen phosphate ion formed in the first ionization step loses another hydrogen ion to form hydrogen phosphate ion:\[ \text{H}_2\text{PO}_4^- (aq) \rightarrow \text{HPO}_4^{2-} (aq) + \text{H}^+ (aq) \]
04

Third Ionization

Finally, the hydrogen phosphate ion loses a third hydrogen ion to become phosphate ion:\[ \text{HPO}_4^{2-} (aq) \rightarrow \text{PO}_4^{3-} (aq) + \text{H}^+ (aq) \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ionization Process
Every acid has a certain capability of releasing hydrogen ions when dissolved in water. This ability is referred to as the ionization process of an acid. The more ions that are released, the more ionized the acid becomes, and its strength increases. In the context of phosphoric acid (H鈧働O鈧), it undergoes a stepwise ionization.

This means it releases hydrogen ions in stages. Each stage sees one hydrogen ion released, starting from H鈧働O鈧 and eventually turning into phosphate ions. Let's break down its ionization:
  • First Ionization: This step releases one H鈦 ion, creating dihydrogen phosphate (H鈧侾O鈧勨伝).
  • Second Ionization: The next H鈦 ion is released, forming hydrogen phosphate (HPO鈧劼测伝).
  • Third Ionization: Finally, the last H鈦 ion is liberated, and a phosphate (PO鈧劼斥伝) ion is produced.
Each ionization produces an additional negative charge in the compound due to the loss of a positively charged hydrogen ion.
Phosphoric Acid
Phosphoric acid, known chemically as H鈧働O鈧, is a weak triprotic acid.

This means it can donate three protons (or hydrogen ions) in an aqueous solution. Triprotic acids have the ability to lose three hydrogen atoms over a series of ionization steps, making the degree of their ionization quite significant in acid-base chemistry.
  • It's used commonly in fertilizers, cleaning products, and even food additives.
  • The weak nature of the acid implies that it does not fully ionize in a solution like strong acids (i.e., sulfuric acid).
  • The multiple ionization steps occurring in phosphoric acid are what make it a unique acid in the study of chemical reactions.
Understanding its behavior in solution is crucial for those studying chemistry because it plays a major role in various chemical processes and functions in biological systems.
Chemical Equations
Chemical equations are symbolic representations of chemical reactions. They show the reactants and products involved, as well as their physical states (such as aqueous or solid).

Balancing these equations is very important because it ensures that the same number of atoms is present on both sides of the equation. This satisfies the law of conservation of mass, where mass is neither created nor destroyed in a chemical reaction.
With phosphoric acid's ionization process, balanced chemical equations illustrate stepwise ionization:
  • First equation: \[ \text{H}_3\text{PO}_4 (aq) \rightarrow \text{H}_2\text{PO}_4^- (aq) + \text{H}^+ (aq) \]
  • Second equation: \[ \text{H}_2\text{PO}_4^- (aq) \rightarrow \text{HPO}_4^{2-} (aq) + \text{H}^+ (aq) \]
  • Third equation: \[ \text{HPO}_4^{2-} (aq) \rightarrow \text{PO}_4^{3-} (aq) + \text{H}^+ (aq) \]
Each step of ionization is represented with its own chemical equation, allowing students to visualize the individual changes that take place at each stage of the reaction.

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Most popular questions from this chapter

Write a balanced equation for reaction of the basic oxide, magnesium oxide, with water.

Balance the following equations, and then classify each as a precipitation, acid-base, or gas-forming reaction. (a) \(\mathrm{Ba}(\mathrm{OH})_{2}(\mathrm{aq})+\mathrm{HCl}(\mathrm{aq}) \rightarrow \mathrm{BaCl}_{2 (\mathrm{aq})+\mathrm{H}_{2} \mathrm{O}(\ell)\) (b) \(\mathrm{HNO}_{3}(\mathrm{aq})+\mathrm{CoCO}_{3}(\mathrm{s}) \rightarrow \mathrm{Co}\left(\mathrm{NO}_{3}\right)_{2}(\mathrm{aq})+\mathrm{H}_{2} \mathrm{O}(\ell)+\mathrm{CO}_{2}(\mathrm{g})\) (c) \(\mathrm{Na}_{3} \mathrm{PO}_{4}(\mathrm{aq})+\mathrm{Cu}\left(\mathrm{NO}_{3}\right)_{2}(\mathrm{aq}) \rightarrow \mathrm{Cu}_{3}\left(\mathrm{PO}_{4}\right)_{2}(\mathrm{s})+\mathrm{NaNO}_{3}(\mathrm{aq})\)

In the following reactions, decide which reactant is oxidized and which is reduced. Designate the oxidizing agent and the reducing agent. (a) \(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}(\mathrm{aq})+3 \mathrm{Sn}^{2+}(\mathrm{aq})+14 \mathrm{H}_{3} \mathrm{O}^{+}(\mathrm{aq}) \rightarrow 2 \mathrm{Cr}^{3+}(\mathrm{aq})+3 \mathrm{Sn}^{4+}(\mathrm{aq})+21 \mathrm{H}_{2} \mathrm{O}(\ell)\) (b) \(\mathrm{FeS}(\mathrm{s})+3 \mathrm{NO}_{3}^{-}(\mathrm{aq})+4 \mathrm{H}_{3} \mathrm{O}^{+}(\mathrm{aq}) \rightarrow 3 \mathrm{NO}(\mathrm{g})+\mathrm{SO}_{4}^{2-}(\mathrm{aq})+\mathrm{Fe}^{3+}(\mathrm{aq})+6 \mathrm{H}_{2} \mathrm{O}(\ell)\)

Predict the products of each precipitation reaction. Balance the equation, and then write the net ionic equation. (a) \(\mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}(\mathrm{aq})+\mathrm{KBr}(\mathrm{aq}) \rightarrow\) (b) \(\mathrm{Ca}\left(\mathrm{NO}_{3}\right)_{2}(\mathrm{aq})+\mathrm{KF}(\mathrm{aq}) \rightarrow\) (c) \(\mathrm{Ca}\left(\mathrm{NO}_{3}\right)_{2}(\mathrm{aq})+\mathrm{Na}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(\mathrm{aq}) \rightarrow\)

Balance the following equations, and then write the net ionic equation. (a) \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{CO}_{3}(\mathrm{aq})+\mathrm{Cu}\left(\mathrm{NO}_{3}\right)_{2}(\mathrm{aq}) \rightarrow \mathrm{CuCO}_{3}(\mathrm{s})+\mathrm{NH}_{4} \mathrm{NO}_{3}(\mathrm{aq})\) (b) \(\mathrm{Pb}(\mathrm{OH})_{2}(\mathrm{s})+\mathrm{HCl}(\mathrm{aq}) \rightarrow \mathrm{PbCl}_{2}(\mathrm{s})+\mathrm{H}_{2} \mathrm{O}(\ell)\) (c) \(\mathrm{BaCO}_{3}(\mathrm{s})+\mathrm{HCl}(\mathrm{aq}) \rightarrow \mathrm{BaCl}_{2}(\mathrm{aq})+\mathrm{H}_{2} \mathrm{O}(\ell)+\mathrm{CO}_{2}(\mathrm{g})\) (d) \(\mathrm{CH}_{3} \mathrm{CO}_{2} \mathrm{H}(\mathrm{aq})+\mathrm{Ni}(\mathrm{OH})_{2}(\mathrm{s}) \rightarrow \mathrm{Ni}\left(\mathrm{CH}_{3} \mathrm{CO}_{2}\right)_{2}(\mathrm{aq})+\mathrm{H}_{2} \mathrm{O}(\ell)\)

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