Chapter 3: Problem 22
The following compounds are water-soluble. What ions are produced by each compound in aqueous solution? (a) KI (b) \(\mathrm{Mg}\left(\mathrm{CH}_{3} \mathrm{CO}_{2}\right)_{2}\) (c) \(\mathrm{K}_{2} \mathrm{HPO}_{4}\) (d) \(\mathrm{NaCN}\)
Short Answer
Expert verified
KI: K鈦 and I鈦; Mg(CH鈧僀O鈧)鈧: Mg虏鈦 and CH鈧僀O鈧傗伝; K鈧侶PO鈧: K鈦 and HPO鈧劼测伝; NaCN: Na鈦 and CN鈦.
Step by step solution
01
Identify the Compound KI
KI is composed of potassium (K) and iodine (I). When KI is dissolved in water, it dissociates into its constituent ions. Potassium iodide will dissociate to form potassium ions (K鈦) and iodide ions (I鈦) in the aqueous solution.
02
Dissociation of KI
In an aqueous solution, the equation for the dissociation of KI can be written as: \[ \text{KI} \rightarrow \text{K}^+ + \text{I}^- \]
03
Identify the Compound Mg(CH鈧僀O鈧)鈧
Mg(CH鈧僀O鈧)鈧 is composed of magnesium (Mg) and acetate (CH鈧僀O鈧傗伝) ions. When dissolved in water, magnesium acetate will dissociate into one magnesium ion (Mg虏鈦) and two acetate ions (CH鈧僀O鈧傗伝).
04
Dissociation of Mg(CH鈧僀O鈧)鈧
The dissociation equation in aqueous solution is: \[ \text{Mg(CH}_3\text{CO}_2)_2 \rightarrow \text{Mg}^{2+} + 2\text{CH}_3\text{CO}_2^- \]
05
Identify the Compound K鈧侶PO鈧
K鈧侶PO鈧 consists of potassium (K) and hydrogen phosphate (HPO鈧劼测伝). In water, each molecule of potassium hydrogen phosphate dissociates into two potassium ions (K鈦) and one hydrogen phosphate ion (HPO鈧劼测伝).
06
Dissociation of K鈧侶PO鈧
The dissociation in water is written as: \[ \text{K}_2\text{HPO}_4 \rightarrow 2\text{K}^+ + \text{HPO}_4^{2-} \]
07
Identify the Compound NaCN
NaCN is made of sodium (Na) and cyanide (CN鈦). When dissolved in water, sodium cyanide dissociates into one sodium ion (Na鈦) and one cyanide ion (CN鈦).
08
Dissociation of NaCN
The dissociation equation is: \[ \text{NaCN} \rightarrow \text{Na}^+ + \text{CN}^- \]
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Water-Soluble Compounds
Water-soluble compounds are substances that can dissolve in water. When these compounds interact with water, they separate into their constituent ions. This separation is known as dissociation and is essential because it allows the compounds to conduct electricity in solution.
Understanding which compounds are water-soluble can help predict their behavior in aqueous solutions. These compounds typically have ionic bonds or are polar molecules, enabling them to interact effectively with the polar water molecules.
Understanding which compounds are water-soluble can help predict their behavior in aqueous solutions. These compounds typically have ionic bonds or are polar molecules, enabling them to interact effectively with the polar water molecules.
- Examples include common salts like sodium chloride (NaCl) and potassium iodide (KI).
- The notion "water-soluble" implies that these substances can split into ions when dissolved in water.
Ion Formation
Ion formation occurs when a compound dissolves in water and dissociates into positive and negative charged particles. These charged particles are called ions.
In the case of ionic compounds, ion formation is quite straightforward. When compounds like KI or NaCN dissolve, they break into their respective ions. For instance, KI dissociates into potassium ions (K鈦) and iodide ions (I鈦).
In the case of ionic compounds, ion formation is quite straightforward. When compounds like KI or NaCN dissolve, they break into their respective ions. For instance, KI dissociates into potassium ions (K鈦) and iodide ions (I鈦).
- Potassium iodide (KI) dissociates into K鈦 and I鈦 ions.
- Magnesium acetate ( Mg(CH鈧僀O鈧)鈧) breaks into Mg虏鈦 and CH鈧僀O鈧傗伝 ions.
Chemical Equations
Chemical equations are symbolic representations of chemical reactions. They show the starting substances (reactants) and the resulting substances (products). When writing equations for dissociation, we aim to illustrate how a compound breaks apart into its ions in an aqueous solution.
Each reaction has reactants on the left and products on the right, separated by an arrow showing the direction of the reaction.
For instance, the dissociation of sodium cyanide (NaCN) can be written as:\[ \text{NaCN} \rightarrow \text{Na}^+ + \text{CN}^- \]
Each reaction has reactants on the left and products on the right, separated by an arrow showing the direction of the reaction.
For instance, the dissociation of sodium cyanide (NaCN) can be written as:\[ \text{NaCN} \rightarrow \text{Na}^+ + \text{CN}^- \]
- Equations must be balanced, meaning the number of atoms and total charge should be equal on both sides of the equation.
- Using proper chemical notation helps in understanding and predicting chemical reactions in aqueous solutions.
Dissociation Reactions
Dissociation reactions refer to the processes where compounds separate into their ions in solution. This is a key concept in aqueous chemistry as it explains how solutes behave in water.
Such reactions illustrate the breakdown of compounds, which might be salts, acids, or bases, into their ionic components. The resultant ions are ready to participate in other chemical reactions or equilibria in solution. For example, when potassium hydrogen phosphate (K鈧侶PO鈧) dissolves in water, it dissociates as follows: \[ \text{K}_2\text{HPO}_4 \rightarrow 2\text{K}^+ + \text{HPO}_4^{2-} \]
Such reactions illustrate the breakdown of compounds, which might be salts, acids, or bases, into their ionic components. The resultant ions are ready to participate in other chemical reactions or equilibria in solution. For example, when potassium hydrogen phosphate (K鈧侶PO鈧) dissolves in water, it dissociates as follows: \[ \text{K}_2\text{HPO}_4 \rightarrow 2\text{K}^+ + \text{HPO}_4^{2-} \]
- These reactions are fundamental to processes like buffering and precipitation in aqueous environments.
- They help explain the solubility and conductivity of ionic substances in water.