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Elemental silicon is oxidized by \(\mathrm{O}_{2}\) to give unknown A. Compound \(A\) is dissolved in molten \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) giving \(\mathrm{B}\). When \(\mathrm{B}\) was treated with aqueous hydrochloric acid, \(\mathrm{C}\) is produced. Identify compound C. (a) \(\mathrm{SiH}_{4}\) (b) \(\mathrm{H}_{4} \mathrm{SiO}_{4}\) (c) \(\mathrm{SiO}_{2}\) (d) \(\operatorname{sicl}_{4}\)

Short Answer

Expert verified
The correct answer is (b) \( \mathrm{H}_{4} \mathrm{SiO}_{4} \).

Step by step solution

01

Oxidation of Silicon

Elemental silicon (Si) is oxidized by oxygen (\( \mathrm{O}_2 \)) to form silicon dioxide \( \mathrm{SiO}_2 \), which we'll call Compound A. The reaction is:\[ \mathrm{Si} + \mathrm{O}_2 \rightarrow \mathrm{SiO}_2 \]
02

Reaction with Sodium Carbonate

Compound A (\( \mathrm{SiO}_2 \)) is dissolved in molten sodium carbonate \( \mathrm{Na}_2 \mathrm{CO}_3 \) to form sodium silicate \( \mathrm{Na}_2\mathrm{SiO}_3 \), which we'll call Compound B.The reaction is:\[ \mathrm{SiO}_2 + \mathrm{Na}_2 \mathrm{CO}_3 \rightarrow \mathrm{Na}_2\mathrm{SiO}_3 + \mathrm{CO}_2 \]
03

Reaction with Hydrochloric Acid

Compound B (\( \mathrm{Na}_2\mathrm{SiO}_3 \)) is treated with aqueous hydrochloric acid \( \mathrm{HCl} \), producing silicic acid \( \mathrm{H}_4\mathrm{SiO}_4 \), which we'll call Compound C.The reaction is:\[ \mathrm{Na}_2\mathrm{SiO}_3 + 2\mathrm{HCl} + 2\mathrm{H_2O} \rightarrow \mathrm{H}_4\mathrm{SiO}_4 + 2\mathrm{NaCl} \]
04

Identify Compound C

Based on the reaction with \( \mathrm{HCl} \), Compound C is silicic acid \( \mathrm{H}_4\mathrm{SiO}_4 \). The correct answer is:(b) \( \mathrm{H}_{4} \mathrm{SiO}_{4} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Oxidation of Silicon
Silicon is a chemical element with the symbol Si. It's a hard and brittle crystalline solid frequently used in electronics. When elemental silicon is subjected to oxygen, a chemical reaction called oxidation occurs. This transformation results in the formation of silicon dioxide, also known as silica. The process can be seen in the equation:
  • \( \mathrm{Si} + \mathrm{O}_2 \rightarrow \mathrm{SiO}_2 \)
This oxidation process is vital as silicon dioxide serves as an essential component in various industrial applications. For instance, it is a critical material in glass manufacturing and ceramics. By understanding how silicon reacts with oxygen, we can harness its properties in technological advancements.
Sodium Silicate Formation
Silicon dioxide, generated from the oxidation of silicon, can interact with sodium carbonate under high-temperature conditions. This reaction forms sodium silicate, a compound often referred to as "water glass." The formation reaction is as follows:
  • \( \mathrm{SiO}_2 + \mathrm{Na}_2 \mathrm{CO}_3 \rightarrow \mathrm{Na}_2\mathrm{SiO}_3 + \mathrm{CO}_2 \)
Sodium silicate has numerous practical applications. It is utilized in detergents, adhesives, and even as a binding agent in the construction industry. This compound's diverse uses are due to its ability to form a glassy structure when dissolved in water, which makes it particularly valuable in coating processes and as a fire protection solution.
Chemical Reactions with Hydrochloric Acid
Sodium silicate, when treated with aqueous hydrochloric acid, undergoes a fascinating chemical transformation. The interaction leads to the production of silicic acid, alongside the by-product sodium chloride (table salt). The reaction can be expressed as:
  • \( \mathrm{Na}_2\mathrm{SiO}_3 + 2\mathrm{HCl} + 2\mathrm{H_2O} \rightarrow \mathrm{H}_4\mathrm{SiO}_4 + 2\mathrm{NaCl} \)
Silicic acid, \( \mathrm{H}_4\mathrm{SiO}_4 \), is an important compound in various chemical processes and serves as a precursor to other silicon-based materials. This reaction illustrates just one way chemical interactions modify substances, highlighting the broader principle of chemical synthesis. Understanding these reactions offers insight into industrial chemistry and how raw materials are transformed into valuable products.

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Most popular questions from this chapter

Sulfur forms a range of compounds with fluorine. Draw Lewis electron dot structures for \(\mathrm{S}_{2} \mathrm{F}_{2}\) (connectivity is FSSF), \(\mathrm{SF}_{2}, \mathrm{SF}_{4}, \mathrm{SF}_{6},\) and \(\mathrm{S}_{2} \mathrm{F}_{10} .\) What is the oxidation number of sulfur in each of these compounds?

In the "contact process" for making sulfuric acid, sulfur is first burned to \(\mathrm{SO}_{2}\). Environmental restrictions allow no more than \(0.30 \%\) of this \(\mathrm{SO}_{2}\) to be vented to the atmosphere. (a) If enough sulfur is burned in a plant to produce \(1.80 \times 10^{6} \mathrm{kg}\) of pure, anhydrous \(\mathrm{H}_{2} \mathrm{SO}_{4}\) per day, what is the maximum amount of \(\mathrm{SO}_{2}\) that is allowed to be exhausted to the atmosphere? (b) One way to prevent any \(\mathrm{SO}_{2}\) from reaching the atmosphere is to "scrub" the exhaust gases with slaked lime, \(\mathrm{Ca}(\mathrm{OH})_{2}\) \(\mathrm{Ca}(\mathrm{OH})_{2}(\mathrm{s})+\mathrm{SO}_{2}(\mathrm{g}) \rightarrow \mathrm{CaSO}_{3}(\mathrm{s})+\mathrm{H}_{2} \mathrm{O}(\ell)\) $$ 2 \mathrm{CaSO}_{3}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{g}) \rightarrow 2 \mathrm{CaSO}_{4}(\mathrm{s}) $$ What mass of \(\mathrm{Ca}(\mathrm{OH})_{2}\) (in kilograms) is needed to remove the \(\mathrm{SO}_{2}\) calculated in part (a)?

Argon is present in dry air to the extent of \(0.93 \%\) by volume. What quantity of argon is present in \(1.00 \mathrm{L}\) of air? If you wanted to isolate 1.00 mol of argon, what volume of air would you need at 1.00 atm pressure and \(25^{\circ} \mathrm{C} ?\)

For each of the third-period elements (Na through Ar), identify the following: (a) whether the element is a metal, nonmetal, or metalloid (b) the color and appearance of the element (c) the state of the element \((s, \ell, \text { or } g\) ) under standard conditions

Calcium oxide, \(\mathrm{CaO}\), is used to remove \(\mathrm{SO}_{2}\) from ower plant exhaust. These two compounds react o give solid \(\mathrm{CaSO}_{3} .\) What mass of \(\mathrm{SO}_{2}\) can be emoved using \(1.2 \times 10^{3} \mathrm{kg}\) of \(\mathrm{CaO} ?\)

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