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Steps have been taken to limit phosphorus in surface water. However, the amounts of nitrogen-containing species in surface water can also be a problem because they also promote excessive growth of algae and water plants. What are likely sources of this nitrogen? What nitrogen compounds are likely to be present in surface water?

Short Answer

Expert verified
Sources include agriculture runoff and sewage. Compounds are nitrate, nitrite, and ammonium.

Step by step solution

01

Identify Nitrogen Sources

Nitrogen in surface water primarily comes from agriculture and urban runoff. Fertilizers used in farming often contain high levels of nitrogen, which can enter water bodies through runoff. Additionally, sewage and industrial waste can contribute nitrogen to surface waters.
02

Determine Common Nitrogen Compounds

The main nitrogen-containing compounds found in surface water include nitrate (NO鈧冣伝), nitrite (NO鈧傗伝), and ammonium (NH鈧勨伜). These compounds are forms of reactive nitrogen that can easily dissolve in water and are often used by algae and plants as nutrients.
03

Explain the Environmental Impact

Excessive nitrogen in water promotes algal blooms, which can lead to oxygen depletion in water bodies. This process, known as eutrophication, can harm aquatic life and degrade water quality, making it unsuitable for consumption and recreation.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Nitrogen Sources
Nitrogen is an essential element for plant growth, but its abundance in surface waters can lead to environmental issues. The primary sources of nitrogen in water bodies are often linked to human activities.
Farmers use fertilizers to support crop growth, which usually contains high levels of nitrogen. During rainfall or irrigation, excess nitrogen may wash off fields, entering nearby rivers and lakes in a process known as agricultural runoff.
  • Agricultural runoff is a significant source of nitrogen, particularly in rural and farming communities.
Another major source is urban runoff. This occurs when water flows over streets, lawns, and other urban areas, picking up nitrogen-rich pollutants.
It then drains into surface waters without treatment.
  • Urban runoff often carries nitrogen from sources such as vehicle emissions, pet waste, and lawn fertilizers.
Sewage and industrial waste can also introduce significant amounts of nitrogen into water systems. Wastewater treatment plants may not always remove all nitrogen, allowing it to pass into surface waters.
Nitrogen Compounds
In surface waters, nitrogen appears in various chemical forms, with each type having different ecological impacts.
The most common nitrogen compounds in such environments are nitrate (NO鈧冣伝), nitrite (NO鈧傗伝), and ammonium (NH鈧勨伜).
  • Nitrate is highly soluble in water and is often found in water bodies affected by agricultural activities.
  • Nitrite, while less abundant, can be particularly harmful to aquatic life even at low concentrations.
  • Ammonium is another form that easily dissolves in water, serving as a direct nutrient source for aquatic plants.
These reactive nitrogen compounds can readily participate in biological processes, often leading to over-fertilization of water ecosystems.
This abundance of nutrients tends to support excessive growth of plants and algae, further contributing to environmental challenges.
Eutrophication
Eutrophication is a process where a water body becomes overly enriched with nutrients, primarily nitrogen and phosphorus, driving excessive algae growth.
When conditions are too nutrient-rich, algal blooms can form, covering the water surface and blocking sunlight from reaching other aquatic life.
  • These blooms can lead to significant oxygen depletion as algae decompose, a situation known as hypoxia.
  • Hypoxia can create "dead zones" where aquatic life cannot survive due to insufficient oxygen.
Moreover, algal blooms can release harmful toxins, posing risks to both aquatic organisms and humans using the water for drinking, swimming, or fishing.
Eutrophication not only threatens marine ecosystems but also affects water quality, making it less safe and less aesthetically pleasing.
Efforts to manage and reduce nutrient runoffs play a crucial role in combating eutrophication, safeguarding aquatic environments for the future.

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Most popular questions from this chapter

Dinitrogen monoxide, \(\mathrm{N}_{2} \mathrm{O}\) (commonly called nitrous oxide), is prepared by the careful decomposition of ammonium nitrate and is used as an oxidizing agent in rocket engines as well as a weak general anesthetic (where you may know it as "laughing gas".). However, it is also known to be a powerful greenhouse gas. In a Science magazine article, it was stated that "Human activities may be causing an unprecedented rise in the terrestrial \(\mathrm{N}_{2} \mathrm{O}\) source. Marine \(\mathrm{N}_{2} \mathrm{O}\) production may also rise substantially as result of eutrophication, warming, and ocean acidification." \([\mathrm{L} . \text { A. Codispoti, } \text {Science}\), Vol. \(327, \text { pp. } 1339-1340,2010 .]\) (a) Draw a Lewis electron dot structure for \(\mathrm{N}_{2} \mathrm{O}\) and specify the formal charge on each atom and the molecular geometry. (b) The atom connections are \(\mathrm{N}-\mathrm{N}-\mathrm{O} .\) Why is the connection \(\mathrm{N}-\mathrm{O}-\mathrm{N}\) not likely? (c) The highest \(\mathrm{N}_{2} \mathrm{O}\) concentration observed in the ocean is about 800 nM (nanomolar). At this concentration, what is the mass of \(\mathrm{N}_{2} \mathrm{O}\) per liter?

Imagine the following experiment: You have a large graduated cylinder containing 100. mL of liquid water at \(0^{\circ} \mathrm{C}\). You drop an ice cube with a volume of \(25 \mathrm{cm}^{3}\) into the cylinder. Ice has a density of \(0.92 \mathrm{g} / \mathrm{cm}^{3},\) less than the density of liquid water, so it floats with \(92 \%\) being under water. (a) To what level will the water in the graduated cylinder rise after adding the ice? (b) Allow the ice to melt. What volume will now be occupied by the liquid water? (One consequence of global warming will be a rise in sea level as ice in the northern and southern regions of the planet melts. However, the effect relates only to melting of ice on land. Melting of floating ice will have no effect on sea levels.

Suppose you find the CO concentration in your home is \(10 .\) ppm by volume at 1.00 atm pressure and \(25^{\circ} \mathrm{C} .\) What is the CO concentration in \(\mathrm{mg} / \mathrm{L}\) and in ppm by mass. (The average molar mass for dry air is \(28.96 \mathrm{g} / \mathrm{mol}\) at 1.00 atm pressure and \(\left.25^{\circ} \mathrm{C} .\right)\)

The refrigerating liquids in air conditioners and refrigerators are largely chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs). Among the latter family of compounds is the refrigerant HCFC-22 \(\left(\mathrm{HCClF}_{2}\right)\). A problem with the use of HCFC-22 is that HFC-23 (trifluoromethane, HCF \(_{3}\) ), a gas with high-global-warming potential, is a byproduct of its production (and also from the production of the widely used polymer Teflon). Discarding HFC-23 safely can be a problem. However, recently a method has been developed to convert it to the valuable catalyst trifluoromethanesulfonic acid, \(\mathrm{CF}_{3} \mathrm{SO}_{3} \mathrm{H}\). Draw an electron dot structure for the acid (which you can think of as sulfuric acid with a \(\mathrm{CF}_{3}\) group in place of one OH group). Indicate the geometry around the \(\mathrm{C}\) and \(\mathrm{S}\) atoms. What is the hybridization of these two atoms?

A 2010 article in Science magazine described "Sewage Treatment with Anammox." IB. Kartal, I. G. Kuenen, and M. C. M. van Loosdrecht, Science, Vol. \(328,\) pp. \(702-703,2010 .\) The authors noted that "Fixed nitrogen such as ammonium and nitrate [ions] must be removed [from sewage] to avoid toxic algal blooms in the environment." One approach to removing ammonium ions is to use ammonium-oxidizing (anammox) bacteria. Two (unbalanced) reactions that are involved are: $$\begin{array}{l}\mathrm{NH}_{4}^{+}(\mathrm{aq})+\mathrm{NO}_{2}^{-}(\mathrm{aq}) \rightarrow \mathrm{N}_{2}(\mathrm{g})+\mathrm{H}_{2} \mathrm{O}(\ell) \\\\\mathrm{NH}_{4}^{+}(\mathrm{aq})+\mathrm{O}_{2}(\mathrm{g}) \rightarrow \mathrm{NO}_{2}^{-}(\mathrm{aq})+\mathrm{H}_{2} \mathrm{O}(\ell)\end{array}$$ Balance these two equations in acid solution.

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