Chapter 9: Problem 24
An expanding gas does \(150.0 \mathrm{J}\) of work on its surroundings at a constant pressure of 1.01 atm. If the gas initially occupied \(68 \mathrm{mL},\) what is the final volume of the gas?
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Chapter 9: Problem 24
An expanding gas does \(150.0 \mathrm{J}\) of work on its surroundings at a constant pressure of 1.01 atm. If the gas initially occupied \(68 \mathrm{mL},\) what is the final volume of the gas?
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How much heat must be absorbed by \(100.0 \mathrm{g}\) of water to raise its temperature from \(30.0^{\circ} \mathrm{C}\) to \(100.0^{\circ} \mathrm{C} ?\)
In a high-temperature gas-phase reaction, methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\) reacts with \(\mathrm{N}_{2}\) to produce \(\mathrm{HCN}\) and \(\mathrm{NH}_{3}\). The reaction is endothermic, requiring \(164 \mathrm{kJ}\) of thermal energy per mole of methanol under standard conditions. a. Write a balanced chemical equation for this reaction. b. Is energy a reactant or a product? c. What is the change in enthalpy under standard conditions if \(60.0 \mathrm{g}\) of \(\mathrm{CH}_{3} \mathrm{OH}(g)\) reacts with excess \(\mathrm{N}_{2}(g),\) forming \(\mathrm{HCN}(g),\) and \(\mathrm{NH}_{3}(g) ?\)
Use standard enthalpies of formation from Appendix 4 to calculate the standard enthalpy of reaction for the following methane-generating reaction of methanogenic bacteria, given \(\Delta H_{f}^{\circ}\) of \(\mathrm{CH}_{3} \mathrm{NH}_{2}(g)=-22.97 \mathrm{kJ} / \mathrm{mol}:\) $$4 \mathrm{CH}_{3} \mathrm{NH}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(\ell) \rightarrow 3 \mathrm{CH}_{4}(g)+\mathrm{CO}_{2}(g)+4 \mathrm{NH}_{3}(g)$$
Use a Born-Haber cycle to calculate the lattice energy of potassium chloride (KCl) from the following data: $$\begin{aligned} &\text { Ionization energy of } \mathrm{K}(g)=419 \mathrm{kJ} / \mathrm{mol}\\\ &\text { Electron affinity of } \mathrm{Cl}(g)=-349 \mathrm{kJ} / \mathrm{mol}\\\ &\text { Energy to sublime } \mathrm{K}(s)=89 \mathrm{kJ} / \mathrm{mol}\\\ &\text { Bond energy of } \mathrm{Cl}_{2}(g)=243 \mathrm{kJ} / \mathrm{mol} \end{aligned}$$ Standard heat of formation of \(\mathrm{KCl}=-436.5 \mathrm{kJ} / \mathrm{mol}\)
The heavier (more dense) hydrocarbons in camp stove fuel are hexanes \(\left(\mathrm{C}_{6} \mathrm{H}_{14}\right)\). a. Calculate the fuel value of \(\mathrm{C}_{6} \mathrm{H}_{14},\) given that \(\Delta H_{\text {comb }}^{\circ}=\) \(-4163 \mathrm{kJ} / \mathrm{mol}\). b. How much heat is released during the combustion of \(1.00 \mathrm{kg}\) of \(\mathrm{C}_{6} \mathrm{H}_{14} ?\) c. How many grams of \(\mathrm{C}_{6} \mathrm{H}_{14}\) are needed to heat \(1.00 \mathrm{kg}\) of water from \(25.0^{\circ} \mathrm{C}\) to \(85.0^{\circ} \mathrm{C} ?\) Assume that all of the heat released during combustion is used to heat the water. d. Assume white gas is \(25 \% \mathrm{C}_{5}\) hydrocarbons (see Problem 9.109) and \(75 \%\) C \(_{6}\) hydrocarbons; how many grams of white gas are needed to heat \(1.00 \mathrm{kg}\) of water from \(25.0^{\circ} \mathrm{C}\) to \(85.0^{\circ} \mathrm{C} ?\)
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