Chapter 9: Problem 17
How can the product of pressure and volume ( \(P-V\) work) have energy units?
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Chapter 9: Problem 17
How can the product of pressure and volume ( \(P-V\) work) have energy units?
These are the key concepts you need to understand to accurately answer the question.
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Calculate \(\Delta E\) when a. \(q=100.0 \mathrm{J} ; w=-50.0 \mathrm{J}\) b. \(q=6.2 \mathrm{kJ} ; w=0.70 \mathrm{L} \cdot\) atm c. \(q=-615 \mathrm{kJ} ; w=-3.25\) kilowatt-hours \((1 \mathrm{kWh}=\) \(3600 \mathrm{kJ})\)
Describe two ways to increase the internal energy of a gas sample.
Explosives called amatols are mixtures of ammonium nitrate and trinitrotoluene (TNT) introduced during World War I when TNT was in short supply. The mixtures can provide \(30 \%\) more explosive power than TNT alone. Above \(300^{\circ} \mathrm{C},\) ammonium nitrate decomposes to \(\mathrm{N}_{2}, \mathrm{O}_{2},\) and \(\mathrm{H}_{2} \mathrm{O} .\) Write a balanced chemical reaction describing the decomposition of ammonium nitrate, and calculate its \(\Delta H_{\mathrm{rxn}}^{\circ}\) using the appropriate \(\Delta H_{\mathrm{f}}^{\circ}\) values from Appendix 4.
Sodium hydroxide is more soluble in hot water than in cold water, but dissolving sodium hydroxide in water is an exothermic process. How can this be the case?
Calculate the lattice energy of sodium oxide \(\left(\mathrm{Na}_{2} \mathrm{O}\right)\) from the following data: Ionization energy of \(\mathrm{Na}(g)=495 \mathrm{kJ} / \mathrm{mol}\) Electron affinity of \(\mathrm{O}(g)\) for 2 electrons \(=603 \mathrm{kJ} / \mathrm{mol}\) Energy to sublime \(\mathrm{Na}(s)=109 \mathrm{kJ} / \mathrm{mol}\) Bond energy of \(\mathrm{O}_{2}(g)=498 \mathrm{kJ} / \mathrm{mol}\) \(\Delta H_{\mathrm{rxn}}\) for \(2 \mathrm{Na}(s)+\frac{1}{2} \mathrm{O}_{2}(g) \rightarrow \mathrm{Na}_{2} \mathrm{O}(s)=-416 \mathrm{kJ} / \mathrm{mol}\)
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