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Silver dissolves in sulfuric acid to form silver sulfate and \(\mathrm{H}_{2},\) but gold does not dissolve in sulfuric acid to form gold sulfate. Which of the two metals is the better reducing agent?

Short Answer

Expert verified
Answer: Silver is the better reducing agent when reacting with sulfuric acid because it dissolves in sulfuric acid and forms silver sulfate, indicating that it's more willing to lose electrons and reduce other substances. Gold, on the other hand, does not dissolve in sulfuric acid, suggesting it is less willing to lose electrons in the reaction.

Step by step solution

01

Write down the balanced chemical equation for the reaction of silver with sulfuric acid

The balanced chemical equation for silver reacting with sulfuric acid is: $$2\mathrm{Ag(s)} + 2\mathrm{H}_{2}\mathrm{SO}_{4}(aq) \rightarrow \mathrm{Ag}_{2}\mathrm{SO}_{4}(s) + 2\mathrm{H}_{2}(g)$$
02

Write down the balanced chemical equation for the reaction of gold with sulfuric acid (if it were to occur)

For comparison purposes, we can also write down the balanced chemical equation for the reaction of gold with sulfuric acid, even though it doesn't actually occur: $$2\mathrm{Au(s)} + 3\mathrm{H}_{2}\mathrm{SO}_{4}(aq) \rightarrow \mathrm{Au}_{2}(\mathrm{SO}_{4})_{3}(s) + \mathrm{3H}_{2}(g)$$
03

Examine the redox behavior of silver and gold during the reactions

A reducing agent is a substance that donates (loses) electrons to another substance in a redox reaction. Let's examine the redox behavior of silver and gold in their respective reactions by identifying the oxidation states of each element before and after the reaction: For silver: - In elemental form, silver has an oxidation state of 0. - In silver sulfate (Ag2SO4), silver has an oxidation state of +1. For gold: - In elemental form, gold has an oxidation state of 0. - In gold sulfate (Au2(SO4)3), gold would have an oxidation state of +3 (if the reaction happened).
04

Determine which metal is the better reducing agent

Since a reducing agent loses electrons in the redox reaction, we can look at how the oxidation state of each metal changes to assess their reducing ability: - Silver goes from an oxidation state of 0 to +1, meaning it loses one electron per atom, reacting with sulfuric acid. - Gold would go from an oxidation state of 0 to +3 if it were to react with sulfuric acid, meaning it would lose three electrons per atom. Since gold doesn't dissolve in sulfuric acid, this indicates that gold is not willing to lose three electrons in the reaction. Therefore, silver, which dissolves in sulfuric acid and forms silver sulfate, is the better reducing agent because it's more willing to lose electrons and reduce other substances.

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