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The solubility of magnesium hydroxide, \(\mathrm{Mg}(\mathrm{OH})_{2},\) in water is \(9.0 \times 10^{-4} \mathrm{g} / 100.0 \mathrm{mL} .\) What volume of \(0.00100 M \mathrm{HNO}_{3}\) is required to neutralize \(1.00 \mathrm{L}\) of a saturated Mg(OH), solution?

Short Answer

Expert verified
Answer: The volume of 0.00100 M HNO鈧 required to neutralize 1.00 L of a saturated Mg(OH)鈧 solution is 0.3084 L.

Step by step solution

01

Write down the balanced chemical equation for the neutralization reaction

The balanced equation for the reaction between magnesium hydroxide and nitric acid is: \(\mathrm{Mg}(\mathrm{OH})_{2}(s) + 2\mathrm{HNO}_{3}(aq) \rightarrow \mathrm{Mg}(\mathrm{NO}_{3})_{2}(aq) + 2\mathrm{H}_{2}\mathrm{O}(l)\)
02

Calculate the moles of magnesium hydroxide in the solution.

Given the solubility of magnesium hydroxide as \(9.0 \times 10^{-4} \mathrm{g} / 100.0 \mathrm{mL}\), we can calculate the moles of magnesium hydroxide in the 1.00 L saturated solution. First, convert solubility from mg/100 mL to g/L: Solubility of Mg(OH)鈧 \(= 9.0 \times 10^{-4} \mathrm{g} / 100.0 \mathrm{mL} \times \frac{1000 \mathrm{mL}}{1 \mathrm{L}} = 9.0 \times 10^{-3} \mathrm{g/L}\) Next, calculate the moles of Mg(OH)鈧 using its molar mass (58.32 g/mol): Moles of Mg(OH)鈧 \(= \frac{9.0 \times 10^{-3} \mathrm{g}}{58.32 \mathrm{g/mol}} = 1.542 \times 10^{-4} \mathrm{mol}\)
03

Determine the moles of nitric acid required for neutralization.

From the balanced chemical equation, one mole of Mg(OH)鈧 reacts with two moles of HNO鈧. Therefore, we can determine the moles of HNO鈧 needed for neutralization: Moles of HNO鈧 = 2 脳 moles of Mg(OH)鈧 Moles of HNO鈧 = 2 脳 1.542 脳 10鈦烩伌 mol = 3.084 脳 10鈦烩伌 mol
04

Calculate the volume of HNO鈧 solution required.

We are given the concentration of HNO鈧 as 0.00100 M (moles per liter). The volume of HNO鈧 solution required for the neutralization can be calculated as: Volume of HNO鈧 = \(\frac{\text{moles of HNO鈧儅}{\text{concentration of HNO鈧儅}\) Volume of HNO鈧 = \(\frac{3.084 \times 10^{-4} \ \mathrm{mol}}{0.00100 \ \mathrm{M}} = 0.3084 \ \mathrm{L}\) So, the volume of 0.00100 M HNO鈧 required to neutralize 1.00 L of a saturated Mg(OH)鈧 solution is 0.3084 L.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Solubility
Solubility is the ability of a substance to dissolve in a solvent, forming a solution at a certain temperature and pressure. It tells us the maximum amount of solute that can be dissolved in a solvent to form a homogeneous mixture, or solution. In the exercise, the solubility of magnesium hydroxide, \(\mathrm{Mg(OH)}_{2}\), is provided as
  • \(9.0 \times 10^{-4}\, \mathrm{g} / 100.0\, \mathrm{mL}\).
This means only a small amount of \(\mathrm{Mg(OH)}_{2}\) can dissolve in water. To use this information for calculations, we need to express solubility in a common measurement, such as grams per liter (g/L). This is achieved by converting the unit to g/L:
  • \(9.0 \times 10^{-4} \times \frac{1000 \mathrm{mL}}{100 \mathrm{mL}} = 9.0 \times 10^{-3}\, \mathrm{g/L}\).
Knowing the solubility helps determine how much of \(\mathrm{Mg(OH)}_{2}\) is available to react in a solution of a given volume.
Moles Calculation
Calculating moles is a fundamental skill in chemistry, important for understanding how much of a substance is involved in a reaction. The number of moles can be calculated using the formula:
  • \(\text{Moles} = \frac{\text{Mass}}{\text{Molar Mass}}\).
For magnesium hydroxide in this problem, the molar mass is crucial. The molar mass of \(\mathrm{Mg(OH)}_{2}\) is 58.32 g/mol. Given the converted solubility:
  • \(9.0 \times 10^{-3}\, \mathrm{g/L}\),
we can find the moles in 1.00 L of solution:
  • Moles of \(\mathrm{Mg(OH)}_{2} = \frac{9.0 \times 10^{-3} \, \mathrm{g}}{58.32 \, \mathrm{g/mol}} = 1.542 \times 10^{-4} \, \text{mol}\).
This calculation tells us how much \(\mathrm{Mg(OH)}_{2}\) is present to participate in further chemical reactions, like neutralization.
Molarity
Molarity is the concentration measure of a solute in a solution. It is expressed as the number of moles of a solute per liter of solution and calculated using:
  • \(\text{Molarity (M)} = \frac{\text{Moles of solute}}{\text{Volume of solution in liters}}\).
In our exercise, we have a \(0.00100 \, \mathrm{M}\) \(\mathrm{HNO}_{3}\) solution, which refers to the molarity. To find the volume of \(\mathrm{HNO}_{3}\) required to neutralize the \(\mathrm{Mg(OH)}_{2}\), we used the relationship:
  • \(\text{Volume of } \mathrm{HNO}_{3} = \frac{3.084 \times 10^{-4} \, \mathrm{mol}}{0.00100 \, \mathrm{M}}\).
This division gives the volume of \(\mathrm{HNO}_{3}\) required to provide the needed moles to react completely with the moles of \(\mathrm{Mg(OH)}_{2}\) in the solution. Understanding molarity helps in making solutions and carrying out accurate neutralization reactions in chemistry.

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