Chapter 23: Problem 64
Why might reductases also be described as reducing agents?
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Chapter 23: Problem 64
Why might reductases also be described as reducing agents?
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Dissolving cobalt(II) nitrate in water gives a beautiful purple solution. There are three unpaired electrons in this cobalt(II) complex. When cobalt(II) nitrate is dissolved in aqueous ammonia and oxidized with air, the resulting yellow complex has no unpaired electrons. Which cobalt complex has the larger crystal field splitting energy \(\Delta_{o} ?\)
What are the names of the following coordination compounds? a. \(\left(\mathrm{NH}_{4}\right)_{3}\left[\mathrm{Co}(\mathrm{CN})_{6}\right]\) b. \(\left[\mathrm{Co}(\mathrm{en})_{2} \mathrm{Cl}\right]\left(\mathrm{NO}_{3}\right)_{2}\) c. \(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}(\mathrm{OH})_{2}\right] \mathrm{Cl}\)
When a transition metal ion such as \(\mathrm{Cu}^{2+}\) is incorporated into a metalloenzyme, is the formation constant likely to be much greater than one \((K > > 1)\) or much less than one \((K < < 1) ?\) \(\mathrm{Cu}^{2+}+\) protein \(\rightleftharpoons\) metalloenzyme \(\quad K=\frac{[\text { metalloenzyme }]}{\left[\mathrm{Cu}^{2+}\right][\text { protein }]}\)
The activation energy for the uncatalyzed decomposition of hydrogen peroxide at \(20^{\circ} \mathrm{C}\) is \(75.3 \mathrm{kJ} / \mathrm{mol} .\) In the presence of the enzyme catalase, the activation energy is reduced to \(29.3 \mathrm{kJ} / \mathrm{mol} .\) Use the following form of the Arrhenius equation, \(R T \ln \left(k_{1} / k_{2}\right)=E_{2,}-E_{2_{1}},\) to calculate how much larger the rate constant of the catalyzed reaction is.
The octahedral crystal field splitting energy \(\Delta_{0}\) of Co(phen) \(_{3}^{3+}\) is \(5.21 \times 10^{-19} \mathrm{J} /\) ion. What is the color of a solution of this complex ion?
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