Chapter 13: Problem 111
Does a catalyst affect both the rate and the rate constant of a reaction?
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Chapter 13: Problem 111
Does a catalyst affect both the rate and the rate constant of a reaction?
These are the key concepts you need to understand to accurately answer the question.
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The rate of a chemical reaction is too slow to measure at room temperature. We could either raise the temperature or add a catalyst. Which would be a better solution for making an accurate determination of the rate constant?
Write the rate laws for the following elementary steps and identify them as uni-, bi-, or termolecular steps: a. \(\mathrm{Cl}(g)+\mathrm{O}_{3}(g) \rightarrow \mathrm{ClO}(g)+\mathrm{O}_{2}(g)\) b. \(2 \mathrm{NO}_{2}(g) \rightarrow \mathrm{N}_{2} \mathrm{O}_{4}(g)\) \(^{\bullet} \mathrm{c} .^{14} \mathrm{C} \rightarrow_{7}^{14} \mathrm{N}+_{-1}^{0} \beta\)
How does the half-life in a first-order reaction depend on the concentration of the reactants?
Write the rate laws for the following elementary steps and identify them as uni-, bi-, or termolecular steps: a. \(\mathrm{SO}_{2} \mathrm{Cl}_{2}(g) \rightarrow \mathrm{SO}_{2}(g)+\mathrm{Cl}_{2}(g)\) b. \(\mathrm{NO}_{2}(g)+\mathrm{CO}(g) \rightarrow \mathrm{NO}(g)+\mathrm{CO}_{2}(g)\) c. \(2 \mathrm{NO}_{2}(g) \rightarrow \mathrm{NO}_{3}(g)+\mathrm{NO}(g)\)
In addition to being studied in the gas phase, the decomposition of \(\mathrm{N}_{2} \mathrm{O}_{5}\) has been evaluated in solution. In carbon tetrachloride (CC1,) at \(45^{\circ} \mathrm{C}\), $$2 \mathrm{N}_{2} \mathrm{O}_{5} \rightarrow 4 \mathrm{NO}_{2}+\mathrm{O}_{2}$$ is a first-order reaction and \(k=6.32 \times 10^{-4} \mathrm{s}^{-1} .\) How much \(\mathrm{N}_{2} \mathrm{O}_{5}\) remains in solution after \(1 \mathrm{h}\) if the initial concentration of \(\mathrm{N}_{2} \mathrm{O}_{5}\) was \(0.50 \mathrm{mol} / \mathrm{L} ?\) What percent of the \(\mathrm{N}_{2} \mathrm{O}_{5}\) has reacted at that point?
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