Chapter 8: Problem 57
Consider the following energy changes: Magnesium oxide exists as \(\mathrm{Mg}^{2+} \mathrm{O}^{2-}\) and not as \(\mathrm{Mg}^{+} \mathrm{O}^{-}\). Explain.
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Chapter 8: Problem 57
Consider the following energy changes: Magnesium oxide exists as \(\mathrm{Mg}^{2+} \mathrm{O}^{2-}\) and not as \(\mathrm{Mg}^{+} \mathrm{O}^{-}\). Explain.
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Arrange the following molecules from most to least polar and explain your order: \(\mathrm{CH}_{4}, \mathrm{CF}_{2} \mathrm{Cl}_{2}, \mathrm{CF}_{2} \mathrm{H}_{2}, \mathrm{CCl}_{4}\), and \(\mathrm{CCl}_{2} \mathrm{H}_{2}\).
Write Lewis structures that obey the octet rule (duet rule for \(\mathrm{H}\) ) for each of the following molecules. a. \(\mathrm{H}_{2} \mathrm{CO}\) b. \(\mathrm{CO}_{2}\) c. HCN Except for \(\mathrm{HCN}\) and \(\mathrm{H}_{2} \mathrm{CO}\), the first atom listed is the central atom. For \(\mathrm{HCN}\) and \(\mathrm{H}_{2} \mathrm{CO}\), carbon is the central atom. Carbon is the central atom in all of these molecules.
Use the following data to estimate \(\Delta H_{\mathrm{f}}^{\circ}\) for potassium chloride. $$ \mathrm{K}(s)+\frac{1}{2} \mathrm{Cl}_{2}(g) \longrightarrow \mathrm{KCl}(s) $$ $$ \begin{array}{lr} \text { Lattice energy } & -690 . \mathrm{kJ} / \mathrm{mol} \\ \text { Ionization energy for } \mathrm{K} & 419 \mathrm{~kJ} / \mathrm{mol} \\\ \text { Electron affinity of Cl } & -349 \mathrm{~kJ} / \mathrm{mol} \\ \text { Bond energy of } \mathrm{Cl}_{2} & 239 \mathrm{~kJ} / \mathrm{mol} \\ \text { Enthalpy of sublimation for } \mathrm{K} & 64 \mathrm{~kJ} / \mathrm{mol} \end{array} $$
Benzene \(\left(\mathrm{C}_{6} \mathrm{H}_{6}\right)\) consists of a six- membered ring of carbon atoms with one hydrogen bonded to each carbon. Write Lewis structures for benzene, including resonance structures.
Think of forming an ionic compound as three steps (this is a simplification, as with all models): (1) removing an electron from the metal; (2) adding an electron to the nonmetal; and (3) allowing the metal cation and nonmetal anion to come together. a. What is the sign of the energy change for each of these three processes? b. In general, what is the sign of the sum of the first two processes? Use examples to support your answer. c. What must be the sign of the sum of the three processes? d. Given your answer to part \(\mathrm{c}\), why do ionic bonds occur? e. Given your above explanations, why is NaCl stable but not \(\mathrm{Na}_{2} \mathrm{Cl} ? \mathrm{NaCl}_{2} ?\) What about \(\mathrm{MgO}\) compared to \(\mathrm{MgO}_{2} ?\) \(\mathrm{Mg}_{2} \mathrm{O} ?\)
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