Chapter 8: Problem 11
Why are some bonds ionic and some covalent?
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Chapter 8: Problem 11
Why are some bonds ionic and some covalent?
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Predict the empirical formulas of the ionic compounds formed from the following pairs of elements. Name each compound. a. \(\mathrm{Li}\) and \(\mathrm{N}\) c. \(\mathrm{Rb}\) and \(\mathrm{Cl}\) b. Ga and \(\mathrm{O}\) d. \(\mathrm{Ba}\) and \(\mathrm{S}\)
What is meant by a chemical bond? Why do atoms form bonds with each other? Why do some elements exist as molecules in nature instead of as free atoms?
When comparing the size of different ions, the general radii trend discussed in Chapter 7 is usually not very useful. What do you concentrate on when comparing sizes of ions to each other or when comparing the size of an ion to its neutral atom?
Write Lewis structures and predict the molecular structures of the following. (See Exercises 105 and 106 .) a. \(\mathrm{OCl}_{2}, \mathrm{KrF}_{2}, \mathrm{BeH}_{2}, \mathrm{SO}_{2}\) b. \(\mathrm{SO}_{3}, \mathrm{NF}_{3}, \mathrm{IF}_{3}\) c. \(\mathrm{CF}_{4}, \mathrm{SeF}_{4}, \mathrm{KrF}_{4}\) d. \(\mathrm{IF}_{5}, \mathrm{AsF}_{5}\) Which of these compounds are polar?
Think of forming an ionic compound as three steps (this is a simplification, as with all models): (1) removing an electron from the metal; (2) adding an electron to the nonmetal; and (3) allowing the metal cation and nonmetal anion to come together. a. What is the sign of the energy change for each of these three processes? b. In general, what is the sign of the sum of the first two processes? Use examples to support your answer. c. What must be the sign of the sum of the three processes? d. Given your answer to part \(\mathrm{c}\), why do ionic bonds occur? e. Given your above explanations, why is NaCl stable but not \(\mathrm{Na}_{2} \mathrm{Cl} ? \mathrm{NaCl}_{2} ?\) What about \(\mathrm{MgO}\) compared to \(\mathrm{MgO}_{2} ?\) \(\mathrm{Mg}_{2} \mathrm{O} ?\)
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