Chapter 8: Problem 10
What is meant by a chemical bond? Why do atoms form bonds with each other? Why do some elements exist as molecules in nature instead of as free atoms?
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Chapter 8: Problem 10
What is meant by a chemical bond? Why do atoms form bonds with each other? Why do some elements exist as molecules in nature instead of as free atoms?
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Which of the following incorrectly shows the bond polarity? Show the correct bond polarity for those that are incorrect. a. \(^{8+} \mathrm{H}-\mathrm{F}^{\delta-}\) d. \(^{\delta}+\mathrm{Br}-\mathrm{Br}^{8}\) b. \(^{\delta+} \mathrm{Cl}-\mathrm{I}^{8}-\) e. \(^{\delta+} \mathrm{O}-\mathrm{P}^{\delta-}\) c. \(^{\delta+} \mathrm{Si}-\mathrm{S}^{8-}\)
Use the following standard enthalpies of formation to estimate the \(\mathrm{N}-\mathrm{H}\) bond energy in ammonia: \(\mathrm{N}(\mathrm{g}), 472.7 \mathrm{~kJ} / \mathrm{mol} ; \mathrm{H}(\mathrm{g})\), \(216.0 \mathrm{~kJ} / \mathrm{mol} ; \mathrm{NH}_{3}(g),-46.1 \mathrm{~kJ} / \mathrm{mol}\). Compare your value to the one in Table \(8.4\).
Some plant fertilizer compounds are \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}, \mathrm{Ca}_{3}\left(\mathrm{PO}_{4}\right)_{2}, \mathrm{~K}_{2} \mathrm{O}\), \(\mathrm{P}_{2} \mathrm{O}_{5}\), and \(\mathrm{KCl}\). Which of these compounds contain both ionic and covalent bonds?
Think of forming an ionic compound as three steps (this is a simplification, as with all models): (1) removing an electron from the metal; (2) adding an electron to the nonmetal; and (3) allowing the metal cation and nonmetal anion to come together. a. What is the sign of the energy change for each of these three processes? b. In general, what is the sign of the sum of the first two processes? Use examples to support your answer. c. What must be the sign of the sum of the three processes? d. Given your answer to part \(\mathrm{c}\), why do ionic bonds occur? e. Given your above explanations, why is NaCl stable but not \(\mathrm{Na}_{2} \mathrm{Cl} ? \mathrm{NaCl}_{2} ?\) What about \(\mathrm{MgO}\) compared to \(\mathrm{MgO}_{2} ?\) \(\mathrm{Mg}_{2} \mathrm{O} ?\)
Oxidation of the cyanide ion produces the stable cyanate ion, \(\mathrm{OCN}^{-}\). The fulminate ion, \(\mathrm{CNO}^{-}\), on the other hand, is very unstable. Fulminate salts explode when struck; \(\mathrm{Hg}(\mathrm{CNO})_{2}\) is used in blasting caps. Write the Lewis structures and assign formal charges for the cyanate and fulminate ions. Why is the fulminate ion so unstable? (C is the central atom in \(\mathrm{OCN}^{-}\) and \(\mathrm{N}\) is the central atom in \(\mathrm{CNO}^{-} .\).)
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