Chapter 8: Problem 10
What is meant by a chemical bond? Why do atoms form bonds with each other? Why do some elements exist as molecules in nature instead of as free atoms?
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Chapter 8: Problem 10
What is meant by a chemical bond? Why do atoms form bonds with each other? Why do some elements exist as molecules in nature instead of as free atoms?
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\(\operatorname{LiI}(s)\) has a heat of formation of \(-272 \mathrm{~kJ} / \mathrm{mol}\) and a lattice energy of \(-753 \mathrm{~kJ} / \mathrm{mol}\). The ionization energy of \(\mathrm{Li}(g)\) is 520 . \(\mathrm{kJ} / \mathrm{mol}\), the bond energy of \(\mathrm{I}_{2}(g)\) is \(151 \mathrm{~kJ} / \mathrm{mol}\), and the electron affinity of \(\mathrm{I}(g)\) is \(-295 \mathrm{~kJ} / \mathrm{mol}\). Use these data to determine the heat of sublimation of \(\operatorname{Li}(s)\).
The second electron affinity values for both oxygen and sulfur are unfavorable (endothermic). Explain.
Some of the important properties of ionic compounds are as follows: i. low electrical conductivity as solids and high conductivity in solution or when molten ii. relatively high melting and boiling points iii. brittleness iv. solubility in polar solvents How does the concept of ionic bonding discussed in this chapter account for these properties?
What do each of the following sets of compounds/ions have in common with each other? a. \(\mathrm{SO}_{3}, \mathrm{NO}_{3}^{-}, \mathrm{CO}_{3}^{2-}\) b. \(\mathrm{O}_{3}, \mathrm{SO}_{2}, \mathrm{NO}_{2}^{-}\)
Order the following species with respect to carbon-oxygen bond length (longest to shortest). $$ \mathrm{CO}, \quad \mathrm{CO}_{2}, \quad \mathrm{CO}_{3}{ }^{2-}, \quad \mathrm{CH}_{3} \mathrm{OH} $$ What is the order from the weakest to the strongest carbonoxygen bond? \(\left(\mathrm{CH}_{3} \mathrm{OH}\right.\) exists as \(\mathrm{H}_{3} \mathrm{C}-\mathrm{OH}\).)
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